Piperidine derivative covalently anchored on uniform spherical mesoporous silica nanoparticle with narrow slit like pores for the synthesis of 2-amino-3, 5-dicarbonitrile-6-arylthio-pyridines

• Authors: Suman Ray , Paramita Das , Asim Bhaumik , Malay Pramanik , Chhanda Mukhopadhyay
• Languages of publication: EN

Abstracts

EN

An organic-inorganic hybrid catalyst (SMSNP-PIP) was prepared by post synthesis grafting of piperidine functionalized organosilane on uniform spherical mesoporous silica nano particle of 600 nm size by using surface hydroxyl groups as anchor point. It was characterized by N2 adsorption analysis, HRTEM, CHN analysis, 13C CP MAS and 29 Si MAS NMR and FTIR analysis. The nano silica particles possess narrow slit-like pores with diameters of 2.6 nm. The wide applicability of this catalyst was probed in the chromatography free synthesis of 2-amino-3,5-dicarbonitrile-6-arylthio-pyridines in water. Synthesis using water as a solvent is of paramount importance for its sustainable green impact. Further, water was the only by-product which added to its attractiveness.

Keywords

EN

spherical mesoporous silica nano particle; organic-inorganic hybrid catalyst; pyridines

• Publisher: De Gruyter Open
• Journal: Recyclable Catalysis
• Year: 2012
• Volume: 1
• Pages: 34-57

Dates

online

18 - 03 - 2014

Contributors

author

Suman Ray

• Department of Chemistry, University of Calcutta, 92 APC Road, Kolkata-700009, India

author

Paramita Das

• Department of Chemistry, University of Calcutta, 92 APC Road, Kolkata-700009, India

author

Asim Bhaumik

• Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India

author

Malay Pramanik

• Department of Materials Science, Indian Association for the Cultivation of Science, Jadavpur, Kolkata 700 032, India

author

Chhanda Mukhopadhyay

• Department of Chemistry, University of Calcutta, 92 APC Road, Kolkata-700009, India

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Identifiers

DOI

10.2478/recat-2014-0001