Pd-anchored functionalized mesoporous materials as robust
and recyclable heterogeneous catalysts for a series of C-C
bond forming reactions

• Authors: John Mondal , Ruth Gomes , Arindam Modak , Asim Bhaumik
• Languages of publication: EN

Abstracts

EN

Pd-catalyzed C-C bond forming reactions have attracted huge interest
not only among the synthetic organic chemists but researchers of various
disciplines for over two decades because a large panorama of value added
organic target molecules can be designed employing this synthesis protocol.
Richard F. Heck, Ei-ichi Negishi and Akira Suzuki have been awarded the
Nobel Prize in Chemistry 2010 for their pioneering works on these palladiumcatalyzed
cross-coupling reactions in organic synthesis. More greener and
eco-friendly synthetic conditions together with the recyclability of the Pdcatalyst
have been continuously hunted over the years. It is essential to know
the different steps and mechanism involved in these C-C coupling reactions
together with the active Pd-sites present at the catalytic surfaces. In this
review we have focused on discussing various protocols involved in the C-C
coupling reactions and gradual developments in Pd-grafted functionalized
mesoporous materials. Recyclability and sustainability of the catalyst along
with their surface modification strategies have been discussed. Catalytic
efficiency of these functionalized mesoporous materials largely depends on
strong binding of the Pd-sites with the support matrix. Thus, discussion on
different types of supports has also been made.

Keywords

EN

C-C cross-coupling reactions; Heck coupling; Functionalized mesoporous materials; Suzuki coupling; Pd-grafting on porous surface

• Publisher: De Gruyter Open
• Journal: Recyclable Catalysis
• Year: 2012
• Volume: 1
• Pages: 10-33

Dates

accepted

03 - 04 - 2013

online

23 - 04 - 2013

received

30 - 11 - 2012

Contributors

author

John Mondal

• Department of Materials Science,
  Indian Association for the Cultivation of Science,
  Jadavpur 700 032, India

author

Ruth Gomes

• Department of Materials Science,
  Indian Association for the Cultivation of Science,
  Jadavpur 700 032, India

author

Arindam Modak

• Department of Materials Science,
  Indian Association for the Cultivation of Science,
  Jadavpur 700 032, India

author

Asim Bhaumik

• Department of Materials Science,
  Indian Association for the Cultivation of Science,
  Jadavpur 700 032, India

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Identifiers

DOI

10.2478/recat-2013-0001