Synergistic extraction of Cr(VI) from Ni(II) and Co(II) by flat sheet supported liquid membranes using TIOA and TBP as carriers

• Authors: Volkan Eyupoglu , Ahmet Surucu , Ahmet Kunduracioglu
• Languages of publication: EN

Abstracts

EN

In present study, the synergistic separation of Cr(VI) has been investigated from synthetic acidic solution containing Cr(VI), Co(II) and Ni(II) by fl at sheet supported liquid membrane (FSSLM) technique using triisooctylamine (TIOA) and tri-n-butyl phosphate (TBP) as carriers. The main goal of the study was based in the exploring of the synergistic effect of TBP on selective extraction of Cr(VI) in presence of Co(II) and Ni(II) ions. The various parameters related with membrane and aqueous solution properties were studied to identify the optimum extraction and stripping conditions of the Cr(VI) through FSSLM. In the optimum conditions, initial mass flux (J0) and separation factors (βCr/Co and βCr/Ni) were obtained as 1.49 x 10-05 (kg/m2.s), 382.2 and 725.3 respectively from aqueous H2SO4 media through Celgard 2500 (Celgard Inc., USA) polymer support. As a result, the considerable synergistic infl uence on selective transport of Cr(VI) through FSSLM using TIOA and TBP as carriers has been identifi ed.

Keywords

EN

flat sheet supported liquid membrane; selective extraction of Cr(VI); TIOA; TBP; synergistic extraction; facilitated mass transfer

• Publisher: De Gruyter Open
• Journal: Polish Journal of Chemical Technology
• Year: 2015
• Volume: 17
• Issue: 2
• Pages: 34-42

Dates

published

1 - 6 - 2015

online

9 - 6 - 2015

Contributors

author

Volkan Eyupoglu

• Cankiri Karatekin University, Department of Chemistry, Faculty of Science, 18100 Cankırı, Turkey

author

Ahmet Surucu

• Pamukkale University, Department of Chemistry, Faculty of Education, 20017, Denizli-Turkey

author

Ahmet Kunduracioglu

• Pamukkale University, Deparment of organic agriculture, Tavas Vacational High School, 20017, Denizli-Turkey

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Identifiers

DOI

10.2478/pjct-2014-0078