Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl

PL EN


Preferences help
enabled [disable] Abstract
Number of results
2014 | 16 | 3 | 80-85

Article title

Processes and Technologies for the Recycling of Spent Fluorescent Lamps

Content

Title variants

Languages of publication

EN

Abstracts

EN
The growing industrial application of rare earth metals led to great interest in the new technologies for the recycling and recovery of REEs from diverse sources. This work reviews the various methods for the recycling of spent fluorescent lamps. The spent fluorescent lamps are potential source of important rare earth elements (REEs) such as: yttrium, terbium, europium, lanthanum and cerium. The characteristics of REEs properties and construction of typical fl uorescent lamps is described. The work compares also current technologies which can be utilized for an efficient recovery of REEs from phosphors powders coming from spent fluorescent lamps. The work is especially focused on the hydrometallurgical and pyrometallurgical processes. It was concluded that hydrometallurgical processes are especially useful for the recovery of REEs from spent fluorescent lamps. Moreover, the methods used for recycling of REEs are identical or very similar to those utilized for the raw ores processing.

Publisher

Year

Volume

16

Issue

3

Pages

80-85

Physical description

Dates

published
1 - 9 - 2014
online
3 - 10 - 2014

Contributors

  • Faculty of Chemistry Nicolaus Copernicus University, ul. Gagarina 7, 87-100 Torun, Poland
  • Czestochowa University of Technology, Department of Chemistry, ul. Armii Krajowej 19, 42-200 Czestochowa, Poland

References

  • 1. Durao, W., Castro, C. & Windmöller, C. (2008). Mercury reduction studies to facilitate the thermal decontamination of phosphor powder residues from spent fluorescent lamps. Waste Management 28, 2311-2319. DOI: 10.1016/j.wasman.2007.10.011.[WoS][Crossref]
  • 2. Chang, T., You, S., Yu, B. & Kong, H. (2007). The fate and management of high mercury-containing lamps from high technology industry. J. Hazard. Mater. 141, 784-792. DOI: 10.1016/j.hazmat.2006.07.045.[Crossref][WoS]
  • 3. Tunsu, C., Retegan, T. & Ekberg, Ch. Sustainable processes development for recycling of fluorescent phosphorous powders - rare earth and mercury separation, Literature report, Chalmers University and Technology, Gothenburg, Sweden, 2012, http://publications.lib.chalmers.se/records/fulltext/local_157270.pdf (24.01.2013).
  • 4. Rey-Raap, N. & Gallardo, A. (2012). Determination of mercury distribution inside spent compact fl uorescent lamps by atomic absorption spectrometry. Waste Management 32, 944-948. DOI: 10.1016/j.wasman.2011.12.001.[WoS][Crossref]
  • 5. Raposo, C., Windmölle, C. & Junior, W. (2003). Mercury speciation in fluorescent lamps by thermal release analysis. Waste Management 23, 879-886. DOI: 10.1016/SO956- -053X(03)00089-8.[Crossref]
  • 6. Rabah, M.A. (2004). Recovery of aluminum, nickel-copper alloys and salts from spent fluorescent lamps. Waste Management 24, 119-126. DOI:10.1016/j.wasman.2003.07.001.[WoS][Crossref]
  • 7. Rabah, M.A. (2008). Recyclables recovery of europium and yttrium metals and some salts from spent fluorescent lamps. Waste Management 28, 318-325. DOI: 10.1016/j.wasman. 2007.02.006.[WoS][Crossref]
  • 8. Hirajima, T., Sasaki, K., Bissombolo, A., Hirai, H., Hamada, M., Tsunekawa, M. (2005). Feasibility of an efficient recovery of rare earth-activated phosphors from waste fl uorescent lamps through dense-medium centrifugation. Sep. Purif. Technol. 44, 197-204. DOI:10.1016/j.seppur.2004.12.014.[Crossref]
  • 9. Hirajima, T., Bissombolo, A., Sasaki, K., Nakayama, K., Hirai, H. & Tsunekawa, M. (2005). Feasibility of a of rare earth phosphors from waste fluorescent lamps. Int. J. Miner. Process. 77, 187-198. DOI:10.1016/j.minpro.2005.05.002.[Crossref]
  • 10. Michelis, I., Ferella, F., Varelli, E.F. & Veglio, F. (2011). Treatment of exhaust fl uorescent lamps to recover yttrium: Experimental and process analyses, Waste Management 31, 2559-2568. DOI:10.1016/j.wasman.2011.07.004.[Crossref][WoS]
  • 11. Ronda, C.R., Jüstel, T. & Nikol, H. (1998). Rare earth phosphors: fundamentals and applications. J. Alloys Comp.275-277, 669-676. PII: S0925-8388(98)00416-2.
  • 12. Rare Earth Elements - EPA/600/R-12/572 Report. 2012. [cited on 2014, Jan 9]. Available from http://nepis.epa.gov/Adobe/PDF/P100EUBC.pdf.
  • 13. Chang, T.Ch., Wang, S.F., You, S.J. & Cheng, A. (2007). Characterization of halophsosphate phosphor powders recovered from the spent fluorescent lamps. J. Environ. Eng. Manage. 17(6), 435-439.
  • 14. Jiang, Y., Shibayama, A., Liu, K. & Fujita, T. (2005). A hydrometallurgical process for extraction of lanthanum, yttrium and gadolinium from spent optical glass. Hydrometallurgy 76, 1-9. DOI: 10.1016/j.hydromet.2004.06.010.[Crossref]
  • 15. Sayilgan, E., Kukrer, T., Civelekoglu, G., Ferella, F., Akcil, A., Veglio, F. & Kitis, M. (2009). A review of technologies for the recovery of metals from spent alkaline and zinc carbon batteries. Hydrometallurgy 97, 158-166. DOI:10.1016/j. hydromet.2009.02.008.[WoS][Crossref]
  • 16. Otto, R. & Wojtalewicz-Kasprzak, A. (2012). Patent No. 20120027651. Chemistry of inorganic compounds treating mixture to obtain metal containing compound rare earth metal.
  • 17. Shimizu, R., Sawada, K., Enokida, Y. & Yamamoto, I. (2005). Supercritical fluid extraction of rare earth elements from luminescent material in waste fluorescent lamps. J. Supercrit. Fluids 33, 235-241. DOI:10.1016/j.supfl u.2004.08.004.[Crossref]
  • 18. Naitou, M., Yoshikawa, M. & Narita, K. (1987). U.S. Patent No. 4650652. Process for recovering highly pure rare earth oxides from a waste rare earth phosphor.
  • 19. Bou-Maroun, E., Chebib, H., Leroy, M.J.F. & Boos, A. (2006). Solvent extraction of lanthanum(III), europium(III) and lutetium(III) by bis(4-acyl-5-hydroxypyrazoles) derivatives. Sep. Purif. Technol. 50, 220-228. DOI: 10.1016/j.seppur.2005.11.029.[Crossref]
  • 20. Sun, X., Wang, J., Li, D. & Li, H. (2006). Synergistic extraction of rare earths by mixture of bis(2,4,4-trimethylpentyl) phosphinic acid and Sec-nonylphenoxy acetic acid. Sep. Purif. Technol. 50, 30-34. DOI: 10.1016/j.seppur.2005.11.004.[Crossref]
  • 21. Morais, C.A. & Ciminelli, V.S.T. (2004). Process development for the recovery of high-grade lanthanum by solvent extraction. Hydrometallurgy 73, 237-244. DOI: 10.1016/j. hydromet.2003.10.008.[Crossref]
  • 22. Singh, D.K., Singh, H. & Mathur, J.N. (2006). Extraction of rare earths and yttrium with high molecular weight carboxylic acids. Hydrometallurgy 81, 184-181. DOI:10.1016/j. hydromet.2005.12.002.[Crossref]
  • 23. Wu, D., Zhang, Q. & Bao, B. (2007). Solvent extraction of Pr and Nd from chloride-acetate medium by 8-hydroquinoline with and without 2-ethylhexyl phosphoric acid mono-2-ethylhexyl ester as an added synergist in heptane diluent. Hydrometallurgy 88, 210-215. DOI: 10.1016/j.hydromet.2007.05.009.[Crossref][WoS]
  • 24. Lu, Y., Bi, Y., Bai, Y. & Liao, W. (2013). Extraction and separation of thorium and rare earths from nitrate medium with p-phosphorylated calixarene. J. Chem. Technol. Biotechnol. http://onlinelibrary.wiley.com (15.03.2013) DOI :10.1002/ jctb.4035/pdf.[Crossref][WoS]
  • 25. Banda, R., Jeon, H., Lee, M. (2012). Solvent extraction separation of Pr and Nd from chloride solution containing La using Cyanex 272 and its mixture with other extractants. Sep. Purif. Technol. 98, 481-489. DOI:10.1016/j.seppur.2012.08.015.[Crossref]
  • 26. El-Nadi, Y.A. (2012). Lanthanum and neodymium from Egyptian monazite: Synergistic extractive separation using organophosphors reagents. Hydrometallurgy 119-120, 23-29. DOI: 10.1016/j.hydromet.2012.03.003.[Crossref][WoS]
  • 27. Belova, V., Voshkin, A., Egorova, N. & Kholkin, A. (2012). Solvent extraction of rare earth metals from nitrate solutions with di(2,4,4-trimethylpentyl)phosphinate of methyltrioctylammonium. J. Molec. Liquids 172, 144-148. DOI: 10.1016/j.molliq.2012.04.012.[Crossref][WoS]
  • 28. El-Hefny, N.E., El-Nadi, Y.A. & Ahmed, I.M. (2011). 18-Crown-6 for the selective extraction and separation of cerium(IV) from nitrate medium containing some lanthanides. Inter. J. Miner. Proces. 101, 58-62. DOI: 10.1016/j. minpro.2011.07.013.[WoS][Crossref]
  • 29. Eskandari Nasab, M.E., Sam, A. & Milani, S.A. (2011). Determination of optimum process conditions for the separation of thorium and rare earth elements by solvent extraction. Hydrometallurgy 106, 141-147. DOI:10.1016/j.hydromet.2010.12.014[WoS][Crossref]
  • 30. Radhika, S., Nagaphani Kumar, B., Lakshmi Kantam, M. & Ramachandra Reddy, B. (2010). Liquid-liquid extraction and separation possibilities of heavy and Ligot rare-earths from phosphoric acid solutions with acidic organophosphors reagents. Sep. Purif. Technol. 75, 295-302. DOI: 10.1016/j. seppur.2010.08.018.[Crossref]
  • 31. Tong, S., Song, N., Jia, Q., Zhou, W. & Liao, W. (2009). Solvent extraction of rare earths from chloride medium with mixtures of 1-phenyl-3-methyl-4-benzoyl-pyrazalone-5 and secoctylphenoxyacetic acid. Sep. Purif. Technol. 69, 97-101. DOI: 10.1016/j.seppur.2009.07.003.[WoS][Crossref]
  • 32. Belova, V.V., Voshkin, A.A., Kholkin, A.I. & Payrtman, A.K. (2009). Solvent extraction of some lanthanides from chloride and nitrate solutions by binary extractants, Hydrometallurgy 97, 198-203. DOI:10.1016/j.hydromet.2009.03.004.[Crossref]
  • 33. El-Sofany, E.A. (2008). Removal of lanthanum and gadolinium from nitrate medium using Aliquat-336 impregnated onto Amberlite XAD-4. J. Hazard. Mater. 153, 948-954. DOI:10.1016/j.jhazmat.2007.09.046.[WoS]
  • 34. Kamio, E., Fujiwara, Y., Matsumoto, M., Valenzuela, F. & Kondo, K. (2008). Investigation on extraction rate of lanthanides with extractant-impregnated microcapsule. Chem. Engine. J. 139, 93-105. DOI: 10.1016/j.cej.2007.07.072.[WoS][Crossref]
  • 35. Kao, H.Ch., Yuang, P. & Juang, R. (2006). Solvent extraction of La(III) and Nd(III) from nitrate solutions with 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester. Chem. Engine. J. 119, 167-174. DOI: 10.1016/j.cej.2006.03.024.[Crossref]
  • 36. Zamani, A.A. & Yaftian, M.R. (2004). Solvent extraction of thorium, lanthanum and europium ions by bis(2-ethylhexyl) phosphoric acid using 2-nitrobenzo-18-crown-6 as ion size selective masking agent. Sep. Purif. Technol. 40, 115-121. DOI: 10.1016/j.seppur.2004.01.012.[Crossref]
  • 37. Jia, Q, Liao, W., Li, D. & Niu, Ch. (2003). Synergistic extraction of lanthanum(III) from chloride medium bymixtures of 1-phenyl-3-methyl-4-benzoyl-pyrazalone-5 and triisobutylphosphine sulphide. Analyt. Chimi. Acta 477, 251-256. PII: S0003-2670(02)01430-7.
  • 38. Innocezi, V., De Michaelis, I., Ferella, F. & Veglio, F. (2013). Recovery of yttrium from cathode ray tubes and lamps’ fl uorescent powders: experimental results and economic simulation. Waste Manag. 33(11), 2390-2396. DOI: 10.1016/j. wasman.2013.06.002. [Crossref]

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_pjct-2014-0055
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.