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2014 | 16 | 2 | 82-86
Article title

Separation of 1,3-Propanediol from Aqueous Solutions by Ion Exchange Chromatography

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EN
Abstracts
EN
1,3-propanediol is a promising monomer with many applications and can be produced by bioconversion of renewable resources. The separation of this product from fermentation broth is a difficult task. In this work, the application of cation exchange resin for the separation of 1,3-propanediol from model aqueous solution was examined. The best effect of separation of 1,3-propanediol from glycerol using sorption method was obtained for H+ resin form, although the observed partition coefficient of 1,3-propanediol was low. On the basis of the results of the sorption of 1,3-propanediol, the ionic forms of the resin were selected and used in the next experiments (H+, Ca2+, Ag+, Na+, Pb2+, Zn2+). The best results in ion exchange chromatography were obtained for cation exchange resin in H+ and Ca2+ form. The use of smaller particle size of resin and a longer length of the column allows to obtain better separation of mixtures.
Publisher

Year
Volume
16
Issue
2
Pages
82-86
Physical description
Dates
online
26 - 6 - 2014
Contributors
  • Poznan University of Technology, Institute of Technology and Chemical Engineering, pl. M. Skłodowskiej-Curie 2, 60-965 Poznan, Poland,
  • Poznan University of Technology, Institute of Technology and Chemical Engineering, pl. M. Skłodowskiej-Curie 2, 60-965 Poznan, Poland,
References
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  • 2. Xiu, Z.L. & Zeng, A.P. (2008). Present state and perspective of downstream processing of biologically produced 1,3-propanediol and 2,3-butanediol. Appl. Microbiol. Biotechnol. 78, 917–926. DOI: 10.1007/s00253-008-1387-4.[Crossref][WoS]
  • 3. Anand, P., Saxena, R.K. & Marwah, R.G. (2011). A novel downstream process for 1,3-propanediol from glycerol-based fermentation. Appl Microbiol Biotechnol 90, 1267–1276. DOI: 10.1007/s00253-011-3161-2.[Crossref][WoS]
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  • 8. Cho, M. H., Joen, S.I., Pyo, S.H., Mun, S. & Kim, J.H. (2006). A novel separation and purification process for 1,3-propanediol. Process Biochem. 41, 739–744. DOI: 10.1016/j. procbio.2005.11.013.[Crossref]
  • 9. Barski, P., Kowalczyk, J., Lindstaedt, A., Puzewicz-Barska, J. & Witt, D. (2012). Evaluation of solid phase extraction for downstream separation of propane-1,3-diol and butan-1-ol from fermentation broth. Process Biochem. 47, 1005–1010. DOI: 10.1016/j.procbio.2012.03.013.[Crossref][WoS]
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  • 11. Luerruk, W., Shotipruk, A., Tantayakom, V., Prasitchoke, P., Muangnapoh, C. (2009). Adsorption of 1,3-propanediol from synthetic mixture using polymeric resin as adsorbents. Front. Chem. Eng. China 3(1), 52–57. DOI: 10.1007/s11705-009-0087-7.[Crossref]
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_pjct-2014-0035
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