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2013 | 15 | 4 | 95-101
Article title

Effect of boron on ZSM-5 catalyst for methanol to propylene conversion

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EN
Abstracts
EN
B-ZSM-5 catalysts were prepared by various modification methods with boric acid, including ion-exchange, impregnation and direct synthesis. The catalysts were characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), NH3-Temperature Programmed Desorption (NH3-TPD), N2 adsorption-desorption, Fourier Transform Infrared spectrometry (FT-IR), 27Al and 11B MAS NMR spectra. The results revealed that the weak acidity of catalysts was significantly increased by modification. The catalytic activity was measured in a fixed bed at 460°C for methanol to propylene (MTP) reaction. The results of MTP reaction showed a great increment of the propylene selectivity for the boron modified samples, especially for the directly synthesized B-ZSM-5 which also displayed high activity and selectivity towards C2 =-C4 = olefins. It was found that the remarkable selectivity strongly depended on the intensity of weak acidity.
Publisher
Year
Volume
15
Issue
4
Pages
95-101
Physical description
Dates
published
1 - 12 - 2013
online
31 - 12 - 2013
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_pjct-2013-0075
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