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2013 | 15 | 4 | 42-48
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A novel functional MgO ∙ SiO2/polyhedral oligomeric silsesquioxane hybrids as an active filler of polypropylene

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New organic/inorganic hybrid fillers were obtained by mechanical modification of magnesium silicate with selected polyhedral oligomeric silsesquioxane and characterized afterwards. MgO ∙ SiO2 was precipitated in a water system. The effect of chemical modification of magnesium silicate surface on their physicochemical properties was determined. Functionalization was carried out with the use of different amount of (1-(3-hydroxypropyl)dimethylsiloxy- 3,5,7,9,11,13,15-hepta(isobutyl)pentacyclo-[, 9.15, 15.17, 13]octasiloxane). The polypropylene composites of 0.5, 1.0 and 1.5 wt.% modified by 10 weight parts by the mass of the filler were also produced. For the obtained polypropylene composites measurements of the tensile strength, Young’s modulus and elongation at break were performed
Physical description
1 - 12 - 2013
31 - 12 - 2013
  • 1. Koyima, Y., Usuki, A., Kawasumi, M., Okada, A., Fukushima, Y., Kurauchi, T. & Kamigaito, O. (1993). Mechanical properties of nylon 6-clay hybrid. J. Mater. Res. 8, 1185-1189. DOI: 10.1557/JMR.1993.1185.[Crossref]
  • 2. Kim, K.M., Keum, D.K. & Chujo, Y. (2003). Organicinorganic polymer hybrids using polyoxazoline initiated by functionalized silsesquioxane. Macromolecules 36, 867-875. DOI: 10.1021/ma021303b.[Crossref]
  • 3. Usuki, A., Kawasumi, M., Kojima, Y., Fukushima, Y., Okada, A., Kurauchi, T. & Kamigaito, O. (1993). Synthesis of nylon 6-clay hybrid. J. Mater. Res. 8, 1179-1184. DOI: 10.1557/ JMR.1993.1179.[Crossref]
  • 4. Lane, R.M., Choi, J. & Lee, I. (2001). Organic inorganic nanocomposites with completely defined interfacial interactions. Adv. Mater. 13, 800-803. DOI: 10.1002/1521-4095(200106)13:11<800::AID-ADMA-800>3.0.CO;2-G.[Crossref]
  • 5. Andrzejewska, E., Marcinkowska, A. & Wegner, K. (2011). Nanocomposites obtained by photopolymerization of (methacrylate monomer)/(methacrylate functionalized polyhedral oligomericsilsesquioxane) system. Polimery 56, 63-66.
  • 6. Chmielewska, D., Barczewski, M. & Sterzyński, T. (2013). A new method of curing epoxy resin by using bis(heptaphenylaluminosilsesquioxane) as a hardener. Polimery 58, 270-275. DOI:
  • 7. Baldi, F., Bignotti, F., Fina, A., Tabuani, D. & Ricco, T. (2007). Mechanical characterization of polyhedral oligomeric silsesquioxane/polypropylene blends. J. Appl. Polym. Sci. 105, 935-943. DOI: 10.1002/app.26142.[Crossref]
  • 8. Zhou, Z., Zhang, Y., Zeng, Z. & Zhang, Y. (2008). Properties of POSS-fi lled polypropylene: comparison of physical blending and reactive blending. J. Appl. Polym. Sci. 110, 3745-3751. DOI: 10.1002/app.29007.[Crossref]
  • 9. Joshi, M., Butola, B.S., Simon, G. & Kukaleva, N. (2006). Rheological and viscoelastic behavior of HDPE/Octamethyl- POSS nanocomposites. Macromolecules 39, 1839-1849. DOI: 10.1021/ma051357.[Crossref]
  • 10. Misra, R., Fu, B.X. & Morgan, S.E. (2007). Surface energetics, dispersion, and nanotribomechanical behavior of POSS/PP hybrid nanocomposites. J. Polym. Sci. B: Polym. Phys. 45, 2441-2445. DOI; 10.1002/polb21261.[WoS][Crossref]
  • 11. Scapini, P., Figueroa, C., Amorim, C., Machado, G., Mauler, R., Crespo, J. & Oliveira, R. (2010). Thermal and morphological properties of high-density polyethylene/ethylene- vinyl acetate copolymer composites with polyhedral oligomeric silsesquioxane nanostructure. Polym Int. 59, 175-180. DOI: 10.1002/pi.2704.[WoS][Crossref]
  • 12. Brown, J.F.Jr. & Vogt, L.H.Jr. (1965). The polycondensation of cyclohexylsilanetriol. J. Am. Chem. Soc. 87, 4313-4317. DOI: 10.1021/ja00947a016.[Crossref]
  • 13. Cordes, D.B., Lickiss, P.D. & Rataboul, F. (2010). Recent development in the chemistry of cubic polyhedral oligoemric oligosilsesquioxanes. Chem. Rev. 110, 2081-2173. DOI: 10.1021/ cr900201r.[Crossref]
  • 14. Constantopoulos, K., Clarke, D., Markovic, E., Uhrig, D., Clarke, S., Matisons, J.G. & Simon, G. (2004). New family of POSS monomers suitable for forming urethane polymerizable coatings. Polym. Prepr. 45, 668.
  • 15. Mammeri, F., Bonhomme, C., Ribot, F., Babonneau, F. & Dire, S. (2005). Modifi cation and characterization of Si-based nanobulding blocks to design hybrid oxide-polymer materials. Mater. Res. Soc. Symp. Proc. 847, 363, EE13.26.1.
  • 16. Cordes, D.B. & Lickiss, P. D., Rataboul F. (2010). Recent developments in the chemistry of cubic polyhedral oligosilsesquioxanes. Chem. Rev. 110, 2081-2173. DOI: 10.1021/cr900201r.[WoS][Crossref]
  • 17. Maciejewski, H., Szubert, K. & Marciniec, B. (2012). New approach to synthesis of functionalised silsesquioxanes via hydrosilylation. Catal. Commun. 24, 1-4. DOI: 10.1016/j. catcom.2012.03.011.[Crossref][WoS]
  • 18. Jakubowska, P., Sterzyński, T. & Królikowski, B. (2008). The properties of polyolefi ns modifi ed with PET powder. J. Appl. Polym. Sci. 109, 1993-1999. DOI: 10.1002/app.27704.[Crossref]
  • 19. Wu, J. & Mather, P.T. (2009). POSS polymers: physical properties and biomaterials applications. Polym. Rev. 49, 25-63. DOI: 10.1080/15583720802656237.[WoS][Crossref]
  • 20. Kallel, T., Nageotte, V., Jaziri, M., Gérard, J.F. & Elleuch, B. (2003). Compatibilization of PE/PS and PE/PP blends. I. Effect of processing conditions and formulation. J. Appl. Polym. Sci. 90, 2475-2484. DOI: 10.1002/app.12873.[Crossref]
  • 21. Zhou, Z., Zhang, Y., Zhang, Y. & Yin, N. (2008) Rheological behavior of polypropylene/octavinyl polyhedral oligomeric silsesquioxane composites. J. Polym. Sci. B: Polym. Phys. 46, 526-533. DOI: 10.1002/polb.21386. [Crossref][WoS]
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