Dimerization of 1-butene in liquid phase over H-NK-MM-BEA type embedded mesoporous materials

• Authors: N. Kumar , P. Mäki-Arvela , S. Fugleberg , T. Yläsalmi , J. Villegas , T. Heikkilä , A.-R. Leino , K. Kordás , M. Tiitta , H. Österholm , T. Salmi , D. Murzin
• Languages of publication: EN

Abstracts

EN

Dimerization of 1-butene in the liquid phase was studied at relatively mild conditions, 523 K under 20 bar over both microporous and embedded microporous mesoporous catalysts. Embedded catalysts were prepared by introducing Beta zeolite nuclei into the gel synthesis of mesoporous material. Three different embedded catalysts with different acidities were prepared and characterized by XRD, nitrogen adsorption, TEM, SEM, pyridine adsorption desorption and ammonia TPD. The embedded materials were shown to be thermally stable up to 1173 K, containing both micro- and mesopores and uniform pores with regular periodicity. According to ammonia TPD the acidity increased with increasing aluminium content. Due to the relatively low reaction temperature, the highest yields of C8 hydrocarbons, 33 mol% at the conversion level of 81% were achieved over an embedded micro-mesoporous catalyst containing Beta zeolite inside the mesoporous and totally 2.4 wt.% aluminium.

Keywords

EN

1-butene; Dimerization; Microporous mesoporous catalyst

• Publisher: De Gruyter Open
• Journal: Catalysis for Sustainable Energy
• Year: 2012
• Volume: 1
• Pages: 1-10

Dates

online

10 - 7 - 2012

accepted

14 - 5 - 2012

received

21 - 4 - 2012

Contributors

author

N. Kumar

• Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo

author

P. Mäki-Arvela

• Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo

author

S. Fugleberg

• Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo

author

T. Yläsalmi

• Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo

author

J. Villegas

• Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo

author

T. Heikkilä

• Laboratory of Industrial Physics, Turku University, FI-20014 Turku/Åbo

author

A.-R. Leino

• Laboratory of Microelectronics and Materials Physics, University of Oulu, PL 4500, FI-90014 Oulu

author

K. Kordás

• Laboratory of Microelectronics and Materials Physics, University of Oulu, PL 4500, FI-90014 Oulu

author

M. Tiitta

• Neste Oil, Technology Center, P.O.B. 310, FI- 06101 Porvoo

author

H. Österholm

• Neste Oil, Technology Center, P.O.B. 310, FI- 06101 Porvoo

author

T. Salmi

• Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo

author

D. Murzin

• Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo

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Identifiers

DOI

10.2478/cse-2012-0001