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2012 | 1 | 1-10
Article title

Dimerization of 1-butene in liquid phase over H-NK-MM-BEA type embedded mesoporous materials

Content
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Languages of publication
EN
Abstracts
EN
Dimerization of 1-butene in the liquid phase was studied at relatively mild conditions, 523 K under 20 bar over both microporous and embedded microporous mesoporous catalysts. Embedded catalysts were prepared by introducing Beta zeolite nuclei into the gel synthesis of mesoporous material. Three different embedded catalysts with different acidities were prepared and characterized by XRD, nitrogen adsorption, TEM, SEM, pyridine adsorption desorption and ammonia TPD. The embedded materials were shown to be thermally stable up to 1173 K, containing both micro- and mesopores and uniform pores with regular periodicity. According to ammonia TPD the acidity increased with increasing aluminium content. Due to the relatively low reaction temperature, the highest yields of C8 hydrocarbons, 33 mol% at the conversion level of 81% were achieved over an embedded micro-mesoporous catalyst containing Beta zeolite inside the mesoporous and totally 2.4 wt.% aluminium.
Publisher

Year
Volume
1
Pages
1-10
Physical description
Dates
online
10 - 7 - 2012
accepted
14 - 5 - 2012
received
21 - 4 - 2012
Contributors
author
  • Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo
  • Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo
author
  • Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo
author
  • Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo
author
  • Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo
author
  • Laboratory of Industrial Physics, Turku University, FI-20014 Turku/Åbo
author
  • Laboratory of Microelectronics and Materials Physics, University of Oulu, PL 4500, FI-90014 Oulu
author
  • Laboratory of Microelectronics and Materials Physics, University of Oulu, PL 4500, FI-90014 Oulu
author
  • Neste Oil, Technology Center, P.O.B. 310, FI- 06101 Porvoo
author
  • Neste Oil, Technology Center, P.O.B. 310, FI- 06101 Porvoo
author
  • Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo
author
  • Process Chemistry Centre, Laboratory of Industrial Chemistry and Reaction Engineering, Åbo Akademi University, FI-20500 Turku/Åbo
References
  • P. Mäki-Arvela, T. Salmi, B. Holmbom, S. Willför, D. Yu. Murzin, D. Yu., Chem. Rev.111, 5638, 2011.
  • S. Larsson, E. Palmqvist, B. Hahn-Hagerdal, C. Tengborg, K. Stenberg, G. Zacchi, N.-O. Nilvebrant, Enz. Microbiol. Technol. 24 (3-4)151, 1999.
  • J. I. Di Cosimo, V. K. Diez, M. Xu, E. Iglesia, C. R. Apesguia, J. Catal. 178, 499, 1998.
  • Y.-S. Hsu, Y.-L. Wang, A.-N. Ko, J. Chin. Chem. Soc. 56 (2), 32, 2009.
  • F. J. Tzompantzi, M. E. Manriquez, J. M. Padilla, G. Angel Del, R. Gomez, A. Mantilla, Catal. Today, 133-135, 154, 2008.
  • C. T. O'Connor, M. Kojima, M, Catal.- Today, 6, 329, 1990.
  • M. Van Oorshcot, M. J. Makee, J. C. Janssen, W. J. Mortier, US Patent 6008426, 1999.
  • M. Henry, B. Bulut, W. Vermandel, B. Sels, P. Jacobs, D. Minoux, N. Nesteranko, S. Van Donk, J. P. Dath, Appl. Catal. A: Gen., 413-414, 62, 2012.
  • J. I. Villegas, N. Kumar, T. Heikkilä, V.-P. Lehto, T. Salmi; D. Yu. Murzin, Topics Catal., 45, 187, 2007.
  • G. G. Podrebarac, F. T. T. Ng, G. L. Rempel, Appl. Catal. A: Gen., 147, 159, 1996.
  • D. Kiessling, K. Hagenau, G. Wendt, A. Barth, R. Schoeliner, React. Kin. Catal. Lett., 39, 89, 1989.
  • N. Kumar, P. Mäki-Arvela, T. Yläsalmi, T. Heikkilä, T. Salmi, D. Yu. Murzin, Micropor. Mesopor. Mater., 147, 127, 2012.
  • A. Matsumoto, H. Chen, K. Tsutsumi, M. Grun, K. Unger, Micropor. Mesopor. Mater., 32, 55, 1999.
  • P. Rao Madhusudhan, M. V. Landau, A. Wolfson, A. M. Shapira-Tchelet, M. Herskowitz, Micropor. Mesop. Mater., 80, 43, 2005.
  • W. Hua, Y. Yue, Z. Gao, J. Mol. Catal. A: Chem., 170, 195, 2001.
  • R. Chal, C. Gérardin, M. Bulut, S. van Donk, ChemCatChem, 3, 67, 2011.
  • N. Kumar, M. Tiitta, T. Salmi, H. Österholm, WO 2006/070073 A1, 2006.
  • C. T. Kresge, M. E., Leonowicz, W. J. Roth, K. D. Schmitt, J. C.; Vartuli, US patent 5198203, 1993.
  • W. Huang, B. Liu, F. Sun, Z. Zhang, X. Bao, Micropor. Mesopor. Mater., 94, 254, 2006.
  • C. Zhang, Q. Liu, Z. Xu, K. Wan, Micropor. Mesopor. Mater., 62, 157, 2003.
  • W. Guo, C. Xiong, L. Huang, Q. Li, J. Mater. Chem., 11 (2001) 1886.
  • K. R. Kloetstra, H. W. Zandbergen, J. C. Jansen, H. van Bekkum, Micropor. Mesopor. Mater., 6, 287, 1996.
  • K. R. Kloetstra, J. C. Jansen, H. Van Bekkum, Prepr. Am. Chem. Soc. Div. Pet Chem., 41, 412, 1996.
  • S. Tanaka, C. Yuan, Y. Miyake, Micropor. Mesopor. Mater., 113, 418, 2008.
  • K. R. Kloetstra, H. Van Bekkum, J. C. Jansen, Chem. Comm. 2281, 1997.
  • A. Karlsson, M. Stöcker, R. Schmid, Micropor. Mesopo. Mater., 27, 181, 1999.
  • G. Zhu, S. Qiu, F. Gao, D. Li, R. Wang, B. Gao, B. Li, Y. Guo, R. Xu, Z. Liu, O. Terasaki, J. Mat. Chem., 11, 1687, 2001.
  • K. R. Kloetstra, H. van Bekkum, J. C. Jansen, Chem. Comm., 2281, 1997.
  • H. Österholm, N. Kumar, M. Lindblad, M. Tiitta, T. Salmi, D. Murzin, Micropor. Mesop. Mat., 154, 124, 2012.
  • R. L. Wadlinger, G. T., Kerr, E. J. Rosinski, US patent 3 308 069 (1975), Mobil Oil Corporation.
  • J. S. Beck, J. C. Vartuli, W. J. Roth, M. E. Leonowicz, C. T. Kresge, K. D. Schmitt, C. T. W. Chu, D. H. Olson, E. W. Sheppard, J. Am. Chem. Soc. 114, 10834, 1992.
  • C. A. Emeis, J. Catal., 141, 347, 1993.
  • M. B. Ewing, J. C. Sanchex Ochoa, J. Chem. Eng. Data, 50, 1543, 2005.
  • S. Wold, Pattern Recog. 8, 127, 1976.
  • J. I. Villegas, D. Kubička, S. P. Reinikainen, G. Addová, R. Kubinec, T. Salmi, D. Yu. Murzin, Talanta, 72, 1573, 2007.
  • HCS Chemistry Ver. 4.0 for Windows. Outokumpu
Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_cse-2012-0001
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