Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl


Preferences help
enabled [disable] Abstract
Number of results
2013 | 34 | 3 | 387-392

Article title

High Pressure Vapour-Liquid Equilibrium of Volatiles in Supercritical Carbon Dioxide


Title variants

Languages of publication



Binary vapour-liquid equilibrium of thymoquinone and carbon dioxide at the isothermal conditions was carried out at temperature 323.15 K and pressures from 6 to 10 MPa. The experimental data were fitted to the Soave-Redlich-Kwong equation of state. Results could be used for selection of process parameters in separation of volatiles from raw oil or for evaluation of existing separation technologies.









Physical description


1 - 09 - 2013
08 - 10 - 2013


  • Łódź University of Technology, Faculty of Process and Environmental Engineering, Department of Heat and Mass Transfer, ul. Wólczańska 213, 90-924 Łódź, Poland
  • Unidade de Bioenergia, Laboratório Nacional de Energia e Geologia, Estrada do Paço do Lumiar 22, 1649-038 Lisboa, Portugal
  • Łódź University of Technology, Faculty of Process and Environmental Engineering, Department of Heat and Mass Transfer, ul. Wólczańska 213, 90-924 Łódź, Poland


  • Berna A., Chafer A., Monton J.B., 2000. Solubilities of essential oil components of orange in supercritical carbon dioxide. J. Chem. Eng. Data, 46, 795-799. DOI: 10.1021/je9903101.[Crossref]
  • Bogel-Łukasik R., Najdanovic-Visak V., Barreiris S., Nunes de Ponte M., 2008. Distribution ratio of lipasecatalyzed reaction products in ionic liquid supercritical CO2 system: Resolution of 2-octanol enantiomers. Ind. Eng. Chem. Res., 47, 4473-4480. DOI: 10.1021/ie0714100.[Crossref][WoS]
  • Brunner G.,1994. Gas extraction: An introduction to fundamentals of supercritical fluids and the application toseparation processes. Steinkopff, Darmstadt & New York, Springer, 30-65.
  • Constantinou L., Gani R., O’Connel J.P., 1995. Estimation of the acentric factor and the liquid molar volume at 298 K using a new group contribution mehod. Fluid Phase Equilibria, 103, 11-22. DOI: 10.1016/0378-3812(94)02593-P.[Crossref]
  • Fonseca J., Simoes S., Nunes da Ponta M., 2003. An apparatus for high pressure VLE measurements using a static mixer. Results for (CO2+ limonene + citral) and (CO2 + limonene + linalool). J. Supercritical Fluids, 25, 7-17. DOI: 10.1016/S0896-8446(02)00085-2.[Crossref]
  • Francisco J.D., Sivik B., 2002. Solubility of three monoterphens, their mixture and eucalyptus leaf oil in dense carbon dioxide. J. Supercritical Fluids, 23, 11-18. DOI: 10.1016/S0896-8446(01)00131-0.[Crossref]
  • Soave G., 1972. Equilibrium constants from a modified Redlich-Kwong equation of state. Chem. Eng. Science, 27 (6), 1197-1203. DOI: 10.1016/0009-2509(72)80096-4.[Crossref]
  • Wagner Z., Pavlicek J., 1993. Vapour-liquid equilibrium in the carbon dioxide ρ-cymene system at high pressure. Fluid Phase Equilibria, 90, 135-141, DOI: 10.1016/0378-3812(93)85008-A. [Crossref]

Document Type

Publication order reference


YADDA identifier

JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.