Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl


Preferences help
enabled [disable] Abstract
Number of results


2005 | 3 | 1 | 104-114

Article title

Excess thermodynamic quantities of D2O water calculated from its Raman O−D stretching spectra


Title variants

Languages of publication



Excess thermodynamic functions of D2O water have been calculated from the vibrationally decoupled O−D stretching spectra of very dilute solutions of HOD in H2O. Comparison of the results with reference calorimetric data for water showed a good correspondence for excess heat capacity above the melting point of ice. The excess enthalpy at the melting point also coincides well with latent heat of melting.










Physical description


1 - 3 - 2005
1 - 3 - 2005


  • Department of Quantum Electronics of Faculty of Physics, Sofia University, 1164, Sofia, Bulgaria
  • CREST, Japan Science and Technology Corporation (JST), National Institute of Advanced Industrial Science and Technology (AIST), Higashi, 305-8562, Tsukuba, Ibaraki, Japan
  • Department of Metallurgical Engineering, University of Utah, 84112, Salt Lake City, UT, U.S.A.
  • Department of Quantum Electronics of Faculty of Physics, Sofia University, 1164, Sofia, Bulgaria


  • [1] G.E. Walrafen:Water: A Comprehensive Treatise, Vol. 1, F. Franks, Plenum Press, New York, 1972.
  • [2] Y. Efimov and Y. Naberukhin: “Distribution of Valent Frequencies and Thermodynamics of Hydrogen Bonding in Water, Calculated on the basis of continuos model from its IR Spectra”,Zh. Strukt. Khim., Vol. 41, (2000), pp. 532–539.
  • [3] M. Georgiev, N. Goutev, Z.S. Nickolov, J.J. Ramsden and G. Georgiev: “Thermodynamic parameters of water calculated from its infrared OH stretching spectrum”,Phil. Mag. B, (2002), pp. 1795–1807.
  • [4] D. Eizenberg and W. Kauzmann:The Structure and Properties of Water, Oxford University Press, Oxford, 1969.
  • [5] V. Zhelyaskov, G. Georgiev, Zh. Nickolov and M. Miteva: “Concentration Raman Study of HOD in D2O”,Mol. Phys.,Vol 64, (1988)pp.1133–1144. http://dx.doi.org/10.1080/00268978800100753[Crossref]
  • [6] Hr. Palamarev and G. Georgiev: “Statistical Distributiin of hydrogen-bonded OH oscillators in HOD on the basis of infrared spectra”Vibr. Spectr., Vol. 7, (1994),pp.255–264. http://dx.doi.org/10.1016/0924-2031(94)85015-1[Crossref]
  • [7] Y. Efimov and Y. Naberukhin: “Fluctuation Theory of Hydrogen Bonding in Liquids”,Faraday Disc. Chem Soc., Vol. 85, (1988), pp. 117–123. http://dx.doi.org/10.1039/dc9888500117[Crossref]
  • [8] A.P. Zhukovsky: “Spectroscopic Confirmation of Continuous Model of Water”,J. Struct. Chem., Vol. 17, (1976), pp. 931–932.
  • [9] Hr. Palamarev and G. Georgiev: “Characterization of OH-stretching vibration in HOD based on the fluctuation model of hydrogen bonds and derived structural data”,J. Mol. Struct.,Vol. 378, (1996),pp.237–248. http://dx.doi.org/10.1016/0022-2860(95)09179-3[Crossref]
  • [10] D.E. Hare and C.M. Sorensen: “Raman spectroscopic study of dilute HOD in liquid H2O in the temperature range −31.5 to 160°C,”J. Chem. Phys.,Vol. 93, (1990),pp.6954–6961. http://dx.doi.org/10.1063/1.459472[Crossref]
  • [11] W. Auer:Kalorimetrische Zustandsgrössen, Landolt-Börnstein 6. Auflage, II Band, 4 Teil, Kl. A. Schäfer and E. Lax., Springer-Verlag, Berlin, 1961, p. 560.
  • [12] G.P. Johari, G. Fleissner, A. Hallbrucker and E. Mayer: “Thermodynamic Continuity between Gassy and Normal Water”,J. Phys. Chem., Vol. 98, (1994) pp. 4719–4725. http://dx.doi.org/10.1021/j100068a038[Crossref]

Document Type

Publication order reference


YADDA identifier

JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.