Full-text resources of PSJD and other databases are now available in the new Library of Science.
Visit https://bibliotekanauki.pl


Preferences help
enabled [disable] Abstract
Number of results


2004 | 2 | 3 | 480-490

Article title

Flow-injection analysis with a small cylindrical wire type electrode


Title variants

Languages of publication



An amperometric detector with a small thin mercury film electrode is described. The device demonstrates advantageous operational characteristics such as small dispersion (D<2) and “memory effect” (me<0.6%), extensive maximum sample frequency (msf −200 samples/h), and high sensitivity. It has been proven useful in flow-injection analysis at a constant potential under hydrodynamic conditions.










Physical description


1 - 9 - 2004
1 - 9 - 2004


  • Department of Analytical Chemistry, University of Plovdiv, 24, Tsar Assen St., 4000, Plovdiv, Bulgaria
  • Department of Analytical Chemistry, University of Plovdiv, 24, Tsar Assen St., 4000, Plovdiv, Bulgaria


  • [1] Zh.I. Denchev, L. Ilcheva and N. Elenkova: “Anodic Stripping Voltammetry of Copper, Lead and Cadmium in Neutral Zinc Plant Electrolyte”, Analytical Laboratory, Vol. 4, (1995), pp. 98–104.
  • [2] Zh.I. Denchev, N.K. Nikolov and L. Ilcheva: “Analytical applications of graphite electrode with Bis(diisopropyloxithiophosphon) Disulfide”, Talanta, Vol. 44, (1997), pp. 749–753. http://dx.doi.org/10.1016/S0039-9140(96)02070-X[Crossref]
  • [3] V.G. Levich: Physico-Chemical Hydrodynamics, (in Russian), Phismathgiz, Moscow, 1959.
  • [4] J. Wang: “Theoretical Treatment of Intermediate Electrolysis Electrochemical Detectors”, Analytica Chimica Acta, Vol. 127, (1981), pp. 157–164. http://dx.doi.org/10.1016/S0003-2670(01)83971-4[Crossref]
  • [5] J.M. Elbicki, D.M. Morgan and S.G. Weber: “Theoretical and Practical Limitations on the Optimisation of Amperometric Detectors”, Analytical Chemistry, Vol. 56, (1984), pp. 978–985. http://dx.doi.org/10.1021/ac00270a026[Crossref]
  • [6] R. Alkire and A.A. Mirarefi: “The Current Distribution Within Tubular Electrodes under Laminar Flow”, Journal Electrochemical Society, Vol. 120, No. 11, (1973), pp. 1507–1515. [Crossref]
  • [7] W.J. Bladel and L.N. Klatt: “Reversible Charge Transfer at the Tubular Platinum Electrode”, Analytical Chemistry, Vol. 38, No. 7, (1966), pp. 879–883. http://dx.doi.org/10.1021/ac60239a021[Crossref]
  • [8] B. Pihlar, L. Kosta and B. Hsistovski: “Amperometric Determination of Cyanide by Use of a Flow-through Electrode”, Talanta, Vol. 26, (1979), pp. 805–810. http://dx.doi.org/10.1016/0039-9140(79)80257-X[Crossref]
  • [9] P.L. Meschi and D.C. Johnson: “The Amperometric Response of Tubular Electrodes Applied to Flow-Injection Determinations”, Analytica Chimica Acta, Vol. 124, (1981), pp. 303–314. http://dx.doi.org/10.1016/S0003-2670(01)93577-9[Crossref]
  • [10] J. Ruzicka and E.H. Hansen: Flow Injection Analysis, John Wiley, New York, 1981.
  • [11] L.J. Magee, Jr. and J. Osteryoung: “Dinamic and Steady-State Response of Electrochemical Detectors Based on Arrays of Small Electrodes”, Analytical Chemistry, Vol. 62, No. 23, (1990), pp. 2625–2631. http://dx.doi.org/10.1021/ac00222a020[Crossref]
  • [12] W.N. Gill and V. Ananthakrishnan: “Laminar Dispersion in Capillaries”, AIChE Journal, Vol. 13, No. 4, (1967), pp. 801–807. http://dx.doi.org/10.1002/aic.690130439[Crossref]
  • [13] S. Melnik and J. Fejes: “Dispersion in Flow-through Injection Analysis”, Chemicke listy, Vol. 81, (1987) pp. 243–253.
  • [14] J.T. Vanderslice, K.K. Stewrt, A.G. Rosefeld and D.J. Higgs: “Laminar Dispertion in Flow Injection Analysis”, Talanta, Vol. 28, (1981), pp. 11–18. http://dx.doi.org/10.1016/0039-9140(81)80131-2[Crossref]
  • [15] J.T. Vanderslice, G.R. Beecher and A.G. Rosefeld: “Dispersion and Diffusion Coefficients in Flow Injection Analysis”, Analytical Chemistry, Vol. 56, (1984), pp. 293–297.

Document Type

Publication order reference


YADDA identifier

JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.