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Journal

2005 | 3 | 2 | 347-360

Article title

Kinetic study of adsorption of some biocompounds at the oil/water interface

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EN

Abstracts

EN
The adsorption kinetics of some local anesthetics, like dibucaine and tetracaine, and of stearic acid from bulk solutions at the oil/water interface was studied by using the pendent drop and ring methods. The anesthetics were dissolved in aqueous solutions (pH 2), and the fatty acid was dissolved in benzene, each biocompound at several different concentrations in bulk solutions. Kinetic equations for Langmuir mechanism of adsorption at oil/water interface were tested. The kinetic analysis shows that Langmuir kinetic approach describes the dynamic interfacial pressures within the limits of the experimental errors over a wide range of time and for different surfactant concentrations in bulk solutions. It is also concluded that this approach allows the calculation of the ratio of the adsorption and desorption rate constants of these biocompounds at the oil/water interface. Obtained results are in substantial agreement with earlier reported data for the surfactant adsorption as, well as with their molecular structure.

Publisher

Journal

Year

Volume

3

Issue

2

Pages

347-360

Physical description

Dates

published
1 - 6 - 2005
online
1 - 6 - 2005

Contributors

  • Department of Orthopaedic Surgery, “Iuliu Hatieganu” University of Medicine, 400028, Cluj-Napoca, Romania
author
  • Department of Physical Chemistry, “Babes-Bolyai” University of Cluj-Napoca, 400028, Cluj-Napoca, Romania

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_BF02476001
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