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Number of results

Journal

2005 | 3 | 2 | 216-229

Article title

Kinetics of electrode reaction coupled to ion transfer across the liquid/liquid interface

Content

Title variants

Languages of publication

EN

Abstracts

EN
In the theoretical model it is assumed that a graphite disk electrode is covered by a thin film of solution of decamethylferrocene (dmfc) and some electrolyte CX in nitrobenzene and immersed in an aqueous solution of the electrolyte MX. Oxidation of dmfc is accompanied by the transfer of anion X
− from water into nitrobenzene since it is also assumed that cations dmfc
+ and C
+ are insoluble in water and cation M
+ is insoluble in nitrobenzene. Kinetic parameters of the electrode reaction can be determined if the total potential difference across the nitrobenzene/water interface is maintained constant by adding the electrolytes CX and MX in concentrations which are much higher than the initial concentration of dmfc in nitrobenzene.

Publisher

Journal

Year

Volume

3

Issue

2

Pages

216-229

Physical description

Dates

published
1 - 6 - 2005
online
1 - 6 - 2005

Contributors

  • Centre for Marine and Environmental Research, “Rudjer Bošković” Institute, P.O. Box 180, HR-10002, Zagreb, Croatia
  • Centre for Marine and Environmental Research, “Rudjer Bošković” Institute, P.O. Box 180, HR-10002, Zagreb, Croatia

References

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Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_2478_BF02475992
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