On applicability of Gibbs thermodynamics to nanoparticles

• Authors: V. Samsonov , A. Bazulev , N. Sdobnyakov
• Languages of publication: EN

Abstracts

EN

The problem of applicability of thermodynamics to small objects has been investigated. It is shown that the Gibbs surface phase method may be extended to nanoparticles if the effective surface tension (the specific excess free energy) is interpreted as a function of the particle radius.

Keywords

EN

Theoretical methods   models and techniques   equilibrium thermodynamics and statistical mechanics   surface thermodynamics   surface energy   surface structure   surface tension   nanoscience   68.03.Cd   81.07.-b   05.70.Np  

• Publisher: De Gruyter Open
• Journal: Open Physics
• Year: 2003
• Volume: 1
• Issue: 3
• Pages: 474-484

Dates

published

1 - 9 - 2003

online

1 - 9 - 2003

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Identifiers

DOI

10.2478/BF02475858