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2004 | 2 | 2 | 323-333

Article title

Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers


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The paper presents a new polymeric polyoxomolybdate cluster with infinite octamolybdate chains cross-linked by iron (II) centers. The layer-type substance contains sodium cations sandwiched between the [Fe(H2O)4Mo8O27]∞ layers. The structure was determined by single crystal X-ray diffraction analysis. Magnetic properties, due to the presence of paramagnetic iron (II) centers, are presented and discussed.










Physical description


1 - 6 - 2004
1 - 6 - 2004


  • Chemistry Department, Babes-Bolyai University, 11 Arany Janos, RO-40028, Cluj-Napoca, Romania
  • Faculty of Chemistry, University of Bielefeld, P.O. Box 100 153, D-33501, Bielefeld, Germany
  • Faculty of Chemistry, University of Bielefeld, P.O. Box 100 153, D-33501, Bielefeld, Germany
  • Faculty of Chemistry, University of Bielefeld, P.O. Box 100 153, D-33501, Bielefeld, Germany


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  • [20] A.F. Orchard:Magnetochemistry, Oxford University Press, oxford, 2003.

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