Infinite octamolybdate chains cross-linked by paramagnetic iron (II) centers

• Authors: Adrian Patrut , Adrian Nicoara , Dragos Margineanu , Michael Koop , Paul Kögerler , Hartmut Bögge , Marc Schmidtmann
• Languages of publication: EN

Abstracts

EN

The paper presents a new polymeric polyoxomolybdate cluster with infinite octamolybdate chains cross-linked by iron (II) centers. The layer-type substance contains sodium cations sandwiched between the [Fe(H2O)4Mo8O27]∞ layers. The structure was determined by single crystal X-ray diffraction analysis. Magnetic properties, due to the presence of paramagnetic iron (II) centers, are presented and discussed.

Keywords

EN

polyoxometalate; molybdenum oxide; metal cluster; layer structure; polymeric chains; X-ray structure; paramagnetism

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2004
• Volume: 2
• Issue: 2
• Pages: 323-333

Dates

published

1 - 6 - 2004

online

1 - 6 - 2004

Contributors

author

Adrian Patrut

author

Adrian Nicoara

author

Dragos Margineanu

• Chemistry Department, Babes-Bolyai University, 11 Arany Janos, RO-40028, Cluj-Napoca, Romania

author

Michael Koop

• Faculty of Chemistry, University of Bielefeld, P.O. Box 100 153, D-33501, Bielefeld, Germany

author

Paul Kögerler

author

Hartmut Bögge

• Faculty of Chemistry, University of Bielefeld, P.O. Box 100 153, D-33501, Bielefeld, Germany

author

Marc Schmidtmann

• Faculty of Chemistry, University of Bielefeld, P.O. Box 100 153, D-33501, Bielefeld, Germany

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Identifiers

DOI

10.2478/BF02475576