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2003 | 1 | 4 | 477-490
Article title

Synthesis and crystal structure of 1-ethyl-3-(phenyl)-1,2,3-triazolium percholorate

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EN
Abstracts
EN
The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-ethyl-3-(phenyl)-1,2,3-triazolium perchlorate (6+). The title compound C10H14Cl N3O4 was isolated and structure was investigated by X-ray crystallography. It crystallizes in the monoclinic space group P21/c with cell parameters a=6.697(4) Å, b=9.724(9) Å, c=19.844(2) Å and Z=4. The final residual factor is R1=0.0471 for 1545 reflections with I>2σ(I). The structure exhibits intermolecular hydrogen bonds.
Publisher

Journal
Year
Volume
1
Issue
4
Pages
477-490
Physical description
Dates
published
1 - 12 - 2003
online
1 - 12 - 2003
Contributors
  • Department of Studies in Physics, University of Mysore, 570 006, Manasagangotri, Mysore, India
  • Department of Studies in Physics, University of Mysore, 570 006, Manasagangotri, Mysore, India
  • Department of Studies in Physics, University of Mysore, 570 006, Manasagangotri, Mysore, India
  • Department of Studies in Physics, University of Mysore, 570 006, Manasagangotri, Mysore, India, jsp@uomphysics.net
  • Department of Studies in Chemistry, University of Mysore, 570 006, Manasagangotri, Mysore, India
author
  • Department of Studies in Chemistry, University of Mysore, 570 006, Manasagangotri, Mysore, India
  • Department of Studies in Chemistry, University of Mysore, 570 006, Manasagangotri, Mysore, India, rangappaks@yahoo.com
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_BF02475229
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