Synthesis and crystal structure of 1-ethyl-3-(phenyl)-1,2,3-triazolium percholorate

• Authors: Beeranahally Doreswamy , Madegowda Mahendra , Sridhar Anandalwar , Javaregowda Prasad , Kempegowda Mantelingu , Basappa , Kanchugarakoppal Rangappa
• Languages of publication: EN

Abstracts

EN

The isolation of stable carbenes of the Arduengo (1a) and Wanzlick (2a) type has prompted us to look for stable nitrenium ions of the related structural type 1-ethyl-3-(phenyl)-1,2,3-triazolium perchlorate (6+). The title compound C10H14Cl N3O4 was isolated and structure was investigated by X-ray crystallography. It crystallizes in the monoclinic space group P21/c with cell parameters a=6.697(4) Å, b=9.724(9) Å, c=19.844(2) Å and Z=4. The final residual factor is R1=0.0471 for 1545 reflections with I>2σ(I). The structure exhibits intermolecular hydrogen bonds.

Keywords

EN

Nitrenium ions; Carbenes; Triazolium perchlorates; Crystal structure

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2003
• Volume: 1
• Issue: 4
• Pages: 477-490

Dates

published

1 - 12 - 2003

online

1 - 12 - 2003

Contributors

author

Beeranahally Doreswamy

• Department of Studies in Physics, University of Mysore, 570 006, Manasagangotri, Mysore, India

author

Madegowda Mahendra

• Department of Studies in Physics, University of Mysore, 570 006, Manasagangotri, Mysore, India

author

Sridhar Anandalwar

• Department of Studies in Physics, University of Mysore, 570 006, Manasagangotri, Mysore, India

author

Javaregowda Prasad

• Department of Studies in Physics, University of Mysore, 570 006, Manasagangotri, Mysore, India

author

Kempegowda Mantelingu

• Department of Studies in Chemistry, University of Mysore, 570 006, Manasagangotri, Mysore, India

author

Basappa

• Department of Studies in Chemistry, University of Mysore, 570 006, Manasagangotri, Mysore, India

author

Kanchugarakoppal Rangappa

• Department of Studies in Chemistry, University of Mysore, 570 006, Manasagangotri, Mysore, India

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Identifiers

DOI

10.2478/BF02475229