New thallium(III) chloride complexes with pyridine carboxylic acids: from molecular compounds to supramolecular associations

• Authors: Monica Toma , Agustín Sánchez , José Casas , José Sordo , María García-Tasende , Eduardo Castellano , Javier Ellena , Ioan Berdan
• Languages of publication: EN

Abstracts

EN

Reactions of TlCl3 with picolinic acid (Hpic), nicotinic acid (Hnic), isonicotinic acid (Hinic) and 3-hydroxy-picolinic acid (H3hpic) afford the isolation of new chlorothallium(III) complexes. The compounds are characterized by IR, Raman and multinuclear NMR (1H,13C,205Tl). The molecular structures of [TlCl2(pic)(Hpic)]·0.5H2O (1), [TlCl2(nic)(Hnic)] (2), [TlCl(inic)2]·0.6C2H5OH (3) and [TlCl(3hpic)2(h3hpic)] (4) are determined by single-crystal X-ray diffraction. A distorted octahedral TlCl2N2O2 core containing the O,N-chelating ligands is achieved in the monomeric complex 1. The coordination polyhedron in compounds 2–4 is pentagonal bipyramidal, i.e. TlCl2NO4 in 2, and TlClN2O4 in 3 and 4, respectively. O,O′,N-Bridging ligands result in a polymer chain for 2 and a three-dimensional polymeric association in 3, while compound 4 is monomeric (O, N-and O,O-chelating ligands).

Keywords

EN

Thallium chloride (III); pyridine-carboxylic acids; complexes; crystal structure

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2003
• Volume: 1
• Issue: 4
• Pages: 441-464

Dates

published

1 - 12 - 2003

online

1 - 12 - 2003

Contributors

author

Monica Toma

• Department of Inorganic Chemistry, “Alexandru Ioan Cuza” University, RO-700506, Iasi, Romania

author

Agustín Sánchez

• Department of Inorganic Chemistry, University of Santiago de Compostela, 15782, Santiago de Compostela, Spain

author

José Casas

• Department of Inorganic Chemistry, University of Santiago de Compostela, 15782, Santiago de Compostela, Spain

author

José Sordo

• Department of Inorganic Chemistry, University of Santiago de Compostela, 15782, Santiago de Compostela, Spain

author

María García-Tasende

• Department of Inorganic Chemistry, University of Santiago de Compostela, 15782, Santiago de Compostela, Spain

author

Eduardo Castellano

• Instituto de Fisica e Quimica de Sao Carlos, Universidade de Sao Carlos, CEP 13560, Sao Carlos, Brasil

author

Javier Ellena

• Instituto de Fisica e Quimica de Sao Carlos, Universidade de Sao Carlos, CEP 13560, Sao Carlos, Brasil

author

Ioan Berdan

• Department of Inorganic Chemistry, University of Santiago de Compostela, 15782, Santiago de Compostela, Spain

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Identifiers

DOI

10.2478/BF02475227