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Journal
2003 | 1 | 4 | 402-426
Article title

Methods for the calculation of occupied volumes in glassy polymers: The lattice integration and the monte carlo methods

Content
Title variants
Languages of publication
EN
Abstracts
EN
A new model for characterizing the free volume of a glassy polymer-gas systems is proposed. An improved method for the calculation of occupied volume per monomer unit was developed within the limits of this model. The model assumptions, error estimates and algorithm efficiencies are described. Using the example of polyvinyltrimethylsilane, it is shown that linear dependences of logarithms of the diffusion and the permeability coefficients on specific accessible volume for inert gases exist.
Publisher

Journal
Year
Volume
1
Issue
4
Pages
402-426
Physical description
Dates
published
1 - 12 - 2003
online
1 - 12 - 2003
Contributors
author
  • A.N.Nesemeyanov Institute of Elementoorganic Compounds, Russian Academy of Sciences, Moscow, Russia, boris@pmc.ineos.ac.ru
author
  • A.V. Topchiev Institute of Petrochemical Synthesis, Russian Academy of Sciences, Moscow, Russia
author
  • A.N.Nesemeyanov Institute of Elementoorganic Compounds, Russian Academy of Sciences, Moscow, Russia, ron@pmc.ineos.ac.ru
References
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_2478_BF02475225
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