Catalytic Supramolecular Photochirogenesis

• Authors: Zhiqiang Yan , Wanhua Wu , Cheng Yang , Yoshihisa Inoue
• Languages of publication: EN

Abstracts

EN

Supramolecular photochirogenesis is a new
strategy for circumventing the inherent difficulties
encountered in conventional photochirogenesis, i.e. the
interactions associated with geometrically less-defined,
short-lived excited states, by confining a prochiral
substrate(s) in a chiral supramolecular environment(s)
prior to photoexcitation. This rather simple, but very
successful, strategy has been applied to a variety of
chiral photoreactions. However, a stoichiometric, or
even excess amount of supramolecular host is often
needed to ensure full complexation of the substrate,
and achieve the optimum stereochemical outcome.
This apparent drawback has recently been removed by
introducing a sensitizing moiety to the supramolecular
host, or by bathochromically shifting the absorption
band of substrate through Lewis acid, or charge-transfer
complexation. Recent progress in catalytic supramolecular
photochirogenesis will be reviewed.

Keywords

EN

photochirogenesis; supuramolecularchemistry; chiral photochemistry; catalysis

• Publisher: De Gruyter Open
• Journal: Supramolecular Catalysis
• Year: 2015
• Volume: 2
• Issue: 1

Dates

accepted

23 - 3 - 2015

received

3 - 2 - 2015

online

3 - 7 - 2015

Contributors

author

Zhiqiang Yan

• Key Laboratory of Green
  Chemistry & Technology of Ministry of Education, College of Chemistry
  and State Key Laboratory of Biotherapy, West China Medical
  School, Sichuan University, 29 Wangjiang Road, Chengdu 610064,
  China

author

Wanhua Wu

• Key Laboratory of Green
  Chemistry & Technology of Ministry of Education, College of Chemistry
  and State Key Laboratory of Biotherapy, West China Medical
  School, Sichuan University, 29 Wangjiang Road, Chengdu 610064,
  China

author

Cheng Yang

• Key Laboratory of Green
  Chemistry & Technology of Ministry of Education, College of Chemistry
  and State Key Laboratory of Biotherapy, West China Medical
  School, Sichuan University, 29 Wangjiang Road, Chengdu 610064,
  China

author

Yoshihisa Inoue

• Department of Applied
  Chemistry, Osaka University, 2-1 Yamada-oka, Suita 565-0871,
  Japan

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Identifiers

DOI

10.1515/supcat-2015-0002