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Journal
2015 | 60 | 4 | 829-835
Article title

Development of the Chalmers Grouped Actinide Extraction Process

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EN
Abstracts
EN
Several solvents for Grouped ActiNide EXtraction (GANEX) processes have been investigated at Chalmers University of Technology in recent years. Four different GANEX solvents; cyclo-GANEX (CyMe4- -BTBP, 30 vol.% tri-butyl phosphate (TBP) and cyclohexanone), DEHBA-GANEX (CyMe4-BTBP, 20 vol.% N,N-di-2(ethylhexyl) butyramide (DEHBA) and cyclohexanone), hexanol-GANEX (CyMe4-BTBP, 30 vol.% TBP and hexanol) and FS-13-GANEX (CyMe4-BTBP, 30 vol.% TBP and phenyl trifluoromethyl sulfone (FS-13)) have been studied and the results are discussed and compared in this work. The cyclohexanone based solvents show fast and high extraction of the actinides but a somewhat poor diluent stability in contact with the acidic aqueous phase. FS-13-GANEX display high separation factors between the actinides and lanthanides and a good radiolytic and hydrolytic stability. However, the distribution ratios of the actinides are lower, compared to the cyclohexanone based solvents. The hexanol-GANEX is a cheap solvent system using a rather stable diluent but the actinide extraction is, however, comparatively low.
Publisher
Journal
Year
Volume
60
Issue
4
Pages
829-835
Physical description
Dates
published
1 - 12 - 2015
accepted
21 - 8 - 2015
received
25 - 6 - 2015
online
30 - 12 - 2015
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_1515_nuka-2015-0115
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