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Journal
2015 | 60 | 3 | 429-434
Article title

Multifrequency EPR study on radiation induced centers in calcium carbonates labeled with 13C

Content
Title variants
Languages of publication
EN
Abstracts
EN
In calcite and aragonite, γ-irradiated at 77 K, several paramagnetic centers were generated and detected by EPR spectroscopy; in calcite, CO3− (orthorhombic symmetry, bulk and bonded to surface), CO33−, NO32−, O3−, and in aragonite CO2− (isotropic and orthorhombic symmetry) depending on the type of calcium carbonate used. For calcium carbonates enriched with 13C more detailed information about the formed radicals was possible to be obtained. In both natural (white coral) and synthetic aragonite the same radicals were identified with main differences in the properties of CO2− radicals. An application of Q-band EPR allowed to avoid the signals overlap giving the characteristics of radical anisotropy.
Publisher
Journal
Year
Volume
60
Issue
3
Pages
429-434
Physical description
Dates
published
1 - 7 - 2015
received
13 - 10 - 2014
accepted
30 - 1 - 2015
online
6 - 8 - 2015
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_1515_nuka-2015-0076
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