Preferences help
enabled [disable] Abstract
Number of results
2015 | 60 | 3 | 417-421
Article title

The MAS NMR study of solid solutions based on the YAG crystal

Title variants
Languages of publication
An 27Al magic angle spinning (MAS) nuclear magnetic resonance (NMR) study of nominally pure and Cr-doped yttrium-aluminum garnet (Y3Al5O12 and Y3Al5O12:Cr) crystals is reported. It has been shown that the doping by Cr of the Y3Al5O12 crystals leads to the variation of the occupation by Al atoms both octahedrally and tetrahedrally coordinated sites of the garnet lattice.
Physical description
1 - 7 - 2015
29 - 10 - 2014
30 - 1 - 2015
6 - 8 - 2015
  • 1. Powell, R. C. (1998). Physics of solid state laser materials. New York: Springer-Verlag.
  • 2. Cheng, Li, Jie, Song, Deyuan, Shen, Yuhui, Cao, Nam Seong, Kim, & Ken-ichi, Ueda. (2000). Flash-lamp-pumped acousto-optic Q-switched Cr-Tm:YAG laser. Optical Rev., 7(1), 58–61.
  • 3. Kalisky, Y. (2006). The physics and engineering of solid state lasers. SPIE Digital Library, ebooks. DOI: 10.1117/3.660249.[Crossref]
  • 4. Hehir, J. P., Henry, M. O., Larkin, J. P., & Imbusch, G. F. (1974). Nature of the luminescence from YAG:Cr3+. J. Phys. C-Solid State Phys., 7(12), 2241.
  • 5. Henderson, B., Gallagher, H. G., Han, T. P. J., & Scott, M. A. (2000) Optical spectroscopy and optimal crystal growth of some Cr4+ doped garnets. J. Phys.-Condens. Matter, 12, 1927–1938.
  • 6. Ubizskii, S. B., Melnyk, S. S., Padlyak, B. V., Matkovskii, A. O., Jankowska-Frydel, A., & Frukacz, Z. (2001) Chromium recharging processes in the Y3A15O12:Mg,Cr single crystal under the reducing and oxidizing annealing influence. Proc. SPIE, 4412, 63.
  • 7. Ubizskii, S. B., Matkovskii, A. O., Syvorotka, I. M., Melnyk, S. S., Kopczynski, K., Mierczyk, Z., & Frukacz, Z. (1999). Growth and characterization of YAG:Cr4+ epitaxial films. Proc. SPIE, 3724, 353.
  • 8. Brog, K. C., Jones, W. H., & Verber, C. M. (1966). 27Al and 89Y nuclear magnetic resonance in yttrium-aluminum garnet. Phys. Lett., 20, 258–260.
  • 9. Grimminck, D. L. A. G., Polman, B. J. W., Arno, P. M., Kentgens, A. P. M., & Meerts, W. L. (2011). EASY-GOING deconvolution: Combining accurate simulation and evolutionary algorithms for fast deconvolution of solid-state quadrupolar NMR spectra. J. Magn. Reson., 211, 114–120. DOI: 10.1016/j.jmr.2011.04.009.[Crossref][WoS]
  • 10. Massiot, D., Bessada, C., Coutures, J. P., & Taulelle, F. (1990). A quantitative study of 27Al MAS NMR in crystalline YAG. J. Magn. Reson., 90, 231–242.
  • 11. Dupree, R., Lewis, M. H., & Smith, M. E. (1988). Structural characterization of ceramic phases with high-resolution 27Al NMR. J. Appl. Crystallogr., 27, 109–116. DOI: 10.1107/S0021889887010069.[Crossref]
  • 12. Vosegaard, T., Byriel, I. P., Pawlak, D. A., Wozniak, K., & Jakobsen, H. J. (1998). Crystal structure studies on the garnet Y3Al5O12 by 27Al single-crystal NMR spectroscopy. J. Am. Chem. Soc., 120, 7900–7904.
  • 13. Florian, P., Gervais, M., Douy, A., Massiot, D., & Coutures, J. P. (2001). A multi-nuclear multiple-field nuclear magnetic resonance study of the Y2O3-Al2O3 phase diagram. J. Phys. Chem. B, 105, 379–391. DOI: 10.1021/jp0008851.[Crossref]
  • 14. Padlyak, B. V., Sergeev, N. A., & Olszewski, M. (2014). The 27Al MAS NMR study of the Y3Al5O12 and Y3Al5O12:Cr garnets. In III Forum Polskiej Grupy EMR/EPR, 23–25 czerwca 2014 (pp. 145–148). Kraków, Poland.
  • 15. Freude, D. (2000). Quadrupolar nuclei in solid-state nuclear magnetic resonance. In R. A. Meyers (Ed.), Encyclopedia of analytical chemistry (pp. 12188–12224). Chichester: John Wiley & Sons Ltd.
  • 16. Kasperovich, V. S., Sodel’, N. E., & Shelyapina, M. G. (2006). Nonempirical cluster calculation of the electric field gradient tensor in yttrium-aluminium garnet Y3Al5O12. Phys. Solid State, 48(9), 1684–1688. DOI: 10.1134/S1063783406090101.[Crossref]
  • 17. Vorob’ev, A. A., Grigor’eva, N. A., Ivanov, S. N., Kasperovich, V. S., Khazanov, E. N., & Charnaya, E. V. (1998). Quadrupole and paramagnetic interaction of 27Al nuclei in mixed yttrium-dysprosium aluminium garnets Y3-xDyxAl5O12. Phys. Solid State, 40(6), 956–959.
  • 18. Bray, P. J. (1999). NMR and NQR studies of boron in vitreous and crystalline borates. Inorg. Chim. Acta, 289, 158–173.
  • 19. Massiot, D., Fayon, F., Capron, M., King, I., Le Calve, S., Alonso, B., Durand, J.-O., Bujoli, B., Gan, Z., & Hoatson, G. (2002). Modelling one- and two-dimensional solid-state NMR spectra. Magn. Reson. Chem., 40, 70–76.
  • 20. d’Espinose de Lacaillerie, J.-B., Fretigny, Ch., & Massiot, D. (2008). MAS NMR spectra of quadrupolar nuclei in disordered solids: The Czjzek model. J. Magn. Reson., 192, 244–251. DOI: 10.1016/j.jmr.2008.03.001.[WoS][Crossref]
  • 21. Menzer, G. (1928). Die kristallstruktur der granate. Z. Kristallographie, 69, 300–396.
  • 22. Geller, S. (1967). Crystal chemistry of the garnets. Z. Kristallographie, 125, 1–47.
  • 23. Charnaya, E. V., Grigoreva, N. A., Ivanov, S. N., Kasperovich, V. S., Khazanov, E. N., & Taranov, A. V. (1995). Structure and ordering of mixed aluminates Y1−xErxAlO3 by NMR, acoustic, and heat pulse techniques. Phys. Status Solidi A-Appl. Mat., 147(2), 313–324. DOI: 10.1002/pssa.2211470203.[Crossref]
Document Type
Publication order reference
YADDA identifier
JavaScript is turned off in your web browser. Turn it on to take full advantage of this site, then refresh the page.