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2015 | 60 | 1 | 109-114
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Structure and Mössbauer spectroscopy studies of mechanically activated (BiFeO3)1−x-(BaTiO3)x solid solutions

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(BiFeO3)1-x-(BaTiO3)x solid solutions with x = 0.1–0.4 and 0.7 were investigated. The ceramics were prepared by mechanical activation technology and subsequent heat treatment. As was proved by X-ray diffraction, increase of BaTiO3 concentration causes a change in the crystalline structure from the rhombohedral structure characteristic of BiFeO3 to a cubic one. 57Fe Mössbauer spectroscopy allowed observation of a gradual transformation from an ordered spin structure of Fe3+ ions to the paramagnetic state with an increase of x.
Physical description
1 - 3 - 2015
12 - 3 - 2015
18 - 6 - 2014
2 - 11 - 2014
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