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Number of results
2014 | 2 | 1 |

Article title

Catalytic synthesis of 2-methyl-1,4-
naphthoquinone in 1%Au/HPS presence

Content

Title variants

Languages of publication

EN

Abstracts

EN
In this paper, theoxidation process of
2 -methylnaphthalene to vitamin K3, using a gold catalyst
systems will be discussed. This catalysis process is based
on the hypercrosslinked polystyrene, synthesized by the
impregnation with solutions of precursors − HAuCl4·2H2O
and Ph3PAuCl. The use of gold catalyst system, which has
been synthesized using Ph3PAuCl, allows to obtain the
main product − 2-methyl-1,4-naphthoquinone − with 72%
yield.

Publisher

Year

Volume

2

Issue

1

Physical description

Dates

accepted
26 - 11 - 2015
online
3 - 2 - 2016
received
9 - 11 - 2015

Contributors

  • Department of
    Biotechnology and Chemistry, Tver State Technical University, A.
    Nikitina 22, Tver, 170026, Russia
  • Department of
    Biotechnology and Chemistry, Tver State Technical University, A.
    Nikitina 22, Tver, 170026, Russia
  • Department of
    Biotechnology and Chemistry, Tver State Technical University, A.
    Nikitina 22, Tver, 170026, Russia

References

  • [1] Ball G. F. M. Vitamins: their role in the human body, BlackwellScience, 2004
  • [2] Wolfgang A. Technologies of the Future: Catalysis, Frankfurt,2000, 97–122
  • [3] Guidetti S. Catalytic liquid- and gas-phase oxidations for thesynthesis of intermediates and specialty chemicals: someexamples of industrial relevance, Tesi di Dottorato di Ricerca,2010
  • [4] Sheldon R. A., Dakka J., Heterogeneous catalytic oxidations inthe manufacture of fine chemicals, Catalysis Today, 1994, 19(2),215-245[Crossref]
  • [5] Сhambers C., Kapoulas V., Marty J.-P., Platzek T., Rastogi S.C.,Opinion on 2-methyl-1-naphthol, 2008, 6-8
  • [6] Selvaraj M., Kandaswamy M, Park D.W., Ha C.S., Highlyselective synthesis of vitamin K3 over mesostructured titaniumcatalysts, Catalysis Today, 2010, 158, 377-384
  • [7] Matveev K.L., Zhizhina E.G., Odyakov V.F., Kotsarenko N.S.,Shmachkova V.P., Catalytic methods for the synthesis ofvitamins K: K3, K4, React. Kinet. Catal.Lett, 1995, 57(2), 375-381[Crossref]
  • [8] Sulman E.M., Matveeva V.G., Doluda V.Yu. et al., AppliedCatalysis B: Environmental, 2010, 94, 200-210
  • [9] Tsyurupa M.P., Davankov V.A., Reactive and FunctionalPolymers, 2006, 66(7), 768-779

Document Type

Publication order reference

Identifiers

YADDA identifier

bwmeta1.element.-psjd-doi-10_1515_cse-2015-0008
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