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Journal
2015 | 13 | 1 |
Article title

Development and validation of the simple
and sensitive spectrophotometric method
of sulphanilamides determination with
4-(2-thiazolylazo)-resorcinol in veterinary preparations

Content
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EN
Abstracts
EN
New simple, rapid, and accurate spectrophotometric techniques for sulphanilamides assay in combination drugs have been elaborated. The method is based on the formation of coloured products of sulphanilamides diazonium salt azoсoupling with heterocyclic azo reagent 4-(2-thiazolylazo)-resorcinol (TAR) in alkaline medium (pH 9.5) with the following measurement of their absorbance at λmax = 615 nm. Formed products are stable for 1 hour at room temperature. Effective molar absorptivities at absorbance maximum 615 nm for disazo dyes were ~ 104 M-1 cm-1. Linear ranges for sulphanilamides determination were 0.5−30.0 μg mL-1. The developed method was used for the suphanilamides determination in tablets, powder, solutions, suspensions and ointments.
EN
Publisher

Journal
Year
Volume
13
Issue
1
Physical description
Dates
accepted
2 - 4 - 2015
online
21 - 10 - 2015
received
22 - 9 - 2014
Contributors
  • Ivan Franko Lviv National University, Chemistry Faculty, Analytical Chemistry Department, Kyrylо & Mefodiy Str., 6, 79005, Lviv, Ukraine
  • State Scientific Research Control Institute of Veterinary Preparations and Fodder Additives, Donetska Str.,11, 79019, Lviv, Ukraine
author
  • Ivan Franko Lviv National University, Chemistry Faculty, Analytical Chemistry Department, Kyrylо & Mefodiy Str., 6, 79005, Lviv, Ukraine
  • Ivan Franko Lviv National University, Chemistry Faculty, Analytical Chemistry Department, Kyrylо & Mefodiy Str., 6, 79005, Lviv, Ukraine
author
  • Ivan Franko Lviv National University, Chemistry Faculty, Analytical Chemistry Department, Kyrylо & Mefodiy Str., 6, 79005, Lviv, Ukraine
  • State Scientific Research Control Institute of Veterinary Preparations and Fodder Additives, Donetska Str.,11, 79019, Lviv, Ukraine
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Document Type
Publication order reference
Identifiers
YADDA identifier
bwmeta1.element.-psjd-doi-10_1515_chem-2015-0139
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