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Article title

Crystallographic and structural characterization
of heterometalic platinum complexes
Part X. Heteropolynuclear pt complexes

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This review covers heteropolynuclear platinum
complexes. There are over sixty examples with heterometal
atoms as partners including non- transition metals, K, Cs,
Mg, Ca, Sr, Tl, Sn, Pb, Zn, Cd, and transition metals: Cu,
Ag, Fe, Co, Ni, Rh and Pd. In addition, there are examples
for the lanthanides, Eu and Yb. The most common are Ag
(x16) and K (x14). The predominant geometries for Pt(II)
is square-planar and for Pt(IV) is octahedral. The overall
structures are complex. In spite of the wide variety of
heterometal atoms partners of platinum, there is “real”
Pt-M bonds only with silver, ranging from 2.678 to 2.943(I)
Å (ave 2.855 Å). The mean Pt-Pt bond distance is 2.869 Å.
Physical description
14 - 1 - 2015
20 - 3 - 2015
9 - 7 - 2014
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