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Article title

Crystallographic and structural characterization
of heterometalic platinum complexes
Part X. Heteropolynuclear pt complexes

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This review covers heteropolynuclear platinum
complexes. There are over sixty examples with heterometal
atoms as partners including non- transition metals, K, Cs,
Mg, Ca, Sr, Tl, Sn, Pb, Zn, Cd, and transition metals: Cu,
Ag, Fe, Co, Ni, Rh and Pd. In addition, there are examples
for the lanthanides, Eu and Yb. The most common are Ag
(x16) and K (x14). The predominant geometries for Pt(II)
is square-planar and for Pt(IV) is octahedral. The overall
structures are complex. In spite of the wide variety of
heterometal atoms partners of platinum, there is “real”
Pt-M bonds only with silver, ranging from 2.678 to 2.943(I)
Å (ave 2.855 Å). The mean Pt-Pt bond distance is 2.869 Å.

Physical description
14 - 1 - 2015
20 - 3 - 2015
9 - 7 - 2014
  • Department of
    Pharmaceutical Analysis and Nuclear Pharmacy, Faculty
    of Pharmacy, Comenius University in Bratislava, Odbojárov 10,
    SK-832 32 Bratislava, Slovak Republic
  • Department of
    Pharmaceutical Analysis and Nuclear Pharmacy, Faculty
    of Pharmacy, Comenius University in Bratislava, Odbojárov 10,
    SK-832 32 Bratislava, Slovak Republic
  • Department of
    Pharmaceutical Analysis and Nuclear Pharmacy, Faculty
    of Pharmacy, Comenius University in Bratislava, Odbojárov 10,
    SK-832 32 Bratislava, Slovak Republic
  • [1] Holloway C.E., Melnik M., Crystallographic and structuralcharacterisation of heterometallic platinum compounds:Part I. Heterobinuclear Pt compounds, Centr. Eur. J. Chem., 2011,9, 501-548.
  • [2] Melník M., Sprušanský O., Holloway C.E., Crystallographicand structural characterization of heterometallic platinumcompounds. Part II. Heterobinuclear Pt compounds with Pt⋯M(M = transition or lantanide metal) > 3.0 Å, Centr. Eur. J. Chem.,2012, 10, 1709-1759.
  • [3] Melník M., Mikuš P., Holloway C.E., Crystalographic andstructural characterization of heterometallic platinumcompounds. Part III: heterotrinuclear compounds, Centr. Eur. J.Chem., 2013, 11, 827-900.
  • [4] Melník M., Mikuš P., Holloway C.E., Crystallographic andstructural characterization of heterometallic platinumcompounds part IV: heterotetranuclear clusters, Centr. Eur. J.Chem., 2013, 11, 1902-1953.
  • [5] Melník M., Mikuš P., Holloway C.E., Crystallographic andstructural characterization of heterometallic platinumcomplexes Part V. Heteropentanuclear complexes, Centr. Eur. J.Chem., 2014, 12, 283-306..
  • [6] Melník M., Mikuš P., Holloway C.E., Crystallographic andstructural characterization of heterometallic platinumcomplexes Part VI. Heterohexanuclear complexes, Centr. Eur. J.Chem., 2014, 12, 1101-1126.
  • [7] Melník M., Mikuš P., Holloway C.E., Crystallographic andstructural characterization of heterometallic platinumcompounds Part VII. Heterohepta and heterooctauclear clusters,Centr. Eur. J. Chem., 2015, 13, 297-316.
  • [8] Melník M., Mikuš P., Holloway C.E., Crystallographic andstructural characterization of heterometallic platinumcompounds Part VIII. Heteronona and heterodecanuclearclusters, Centr. Eur. J. Chem., 2015, 13, 425-447.
  • [9] Melník M., Mikuš P., Holloway C.E., Crystallographic andstructural characterization of heterometallic platinumcompounds Part IX. Heterooligonuclear clusters, Centr. Eur. J.Chem., 2015, 13, 701-724.
  • [10] Yamaguchi T., Yamazaki F., Ito T., A short platinum to silverdative bond and its application in the construction of extendedstructures: syntheses and structures of Ag2[Pt(ox)2]•2H2O and[Ag(H2O)]2 [Ag2(CF3SO3)4][Pt(acac)2]2, J. Chem. Soc., DaltonTrans., 1999, 273-274.[Crossref]
  • [11] Kobayashi A., Sasaki Y., Kobayashi H., Structure ofcommensurate peierls state of Rb1.67Pt(C2O4)2•1.5H2O, 1978,7, 1167-1170.; Structural Studies of Commensurate Peierls Stateof Rb1.67[Pt(C2O4)2]•1.5H2O, 1979, 52, 3682-3691.
  • [12] Kobayashi H., Shirotani I., Kobayashi A., Sasaki Y., Sinusoidallymodulated structure of a partially oxidized platinum complex,K1.6Pt(C2O4)2•1.2H2O, Solid Sate Commun.,1977, 23, 409-413.
  • [13] Mattes R., Krogmann K., Die Kristallstruktur vonKaliumdioxalatoplatinat (II), K2Pt(C2O4)22 •2H2O, Z. Anorg.Allg. Chem., 1964, 332, 247-256.
  • [14] Kobayashi A., Kondo H., Sasaki Y., Kobayashi H., Underhill A.E.,Watkins D.M., Structural Studies of Partially Oxidized OnedimensionalBis(oxalato)platinate Salts Containing BivalentCations: Ni0.84[Pt(C2O4)2]. 6H2O, Bull. Chem. Soc. Jpn.,1982,55, 2074-2083.
  • [15] Schultz A.J., Underhill A.E., Williams J.M., Preparation andcrystal structure of the new paramagnetic one-dimensionalconductor Co0.83[Pt(C2O4)2].6H2O, Inorg. Chem., 1978, 17,1313-1315.
  • [16] Krogmann K., Strukturen mit Pt-Ketten. II. „Violettes”Magnesiumdioxalatoplatinat Mg0,82[Pt(C2O4)2] • 5,3 H2O, Z.Anorg. Allg. Chem., 1968, 358, 97-110.
  • [17] Krogmann K., Strukturen mit Platin-Ketten IV. RoteDioxalatoplatinate(II), Z. Naturforsch., 1968, 23b, 1012-1018.
  • [18] Mizuno M., New 1-D platinum chain compounds withcommensurate peierls structure, Synthetic Met., 1987, 19, 963-966.; Lee K.H., Kim J.H., Mizuno M., Preparation and Propertiesof New Metal-chain Compounds with Commensurate PeierlsStructure, Bull. Korean Chem. Soc., 1987, 8, 137-139.[Crossref]
  • [19] Bekaroglu O., , Sharif M.E., Endres H., Keller H.J., A platinumzigzag chain in is(ethylenediamine)copper(II) bis(oxalato)platinate(II): the crystal structure of [Cu(C2N2H8)2][Pt(C2O4)2],Acta Crystallogr., Sect. B, 1976, 32, 2983-2986.[Crossref]
  • [20] Endres H. , Liebich–Brudy G., [Bis(oxamidoxim)nickeI(II)]-[Bis(oxalato)platinat(II)]-Dihydrat x [Bis(oxamidoximato)nickel(II)]:Getrennte parallele Stapel im Verhältnis 2:1, Z.Naturforsch., 1986, 41b, 339-345.
  • [21] Dunham S.O., Larsen R.D., Abbott E.H., Nuclear magneticresonance investigation of the formation of oxalato, malonato,and 2-methylmalonato complexes of platinum(II). Crystal andmolecular structures of potassium anti-bis(2-methylmalonato)platinate(II) dihydrate and potassium dichloro(oxalato)platinate(II) hydrate, Inorg. Chem., 1991, 30, 4328-4335.
  • [22] Cherkashina N.V., Kozitsyna N.Yu., Aleksandrov G.G., VargaftikM.N., Moiseev I.I., Synthesis and structure of the first platinum(II)pivalato complexes, Mendeleev Commun., 2002, 12, 49-50..[Crossref]
  • [23] Schöllhorn H., Thewalt U., Lippert B., 1-Methyluracil (Hmeu) astetradentate ligand: crystal structure of trans-(NH3)2Pt(meu)2Ag2(NO3)2(H2O)•H2O, J. Chem. Soc. Chem. Commun., 1984, 769-770.; Dieter I., Lippert B., Schöllhorn H., Thewalt U., CoordinationChemistry of fra/is-(NH3)2Pt(II) with Uracil Nucleobases.AComparison with cis-(NH3)2Pt(II), Z. Naturforsch., 1990, 45b,731-740.[Crossref]
  • [24] Erxleben A., Lippert B., First examples of polymeric mixedmetal(Pt-Ag) complexes containing single acetamidatebridges: cis-[(NH3)2Pt(NHCOMe)2Ag]-NO3.4H2O and trans-[(NH3)2Pt(NHCOMe)2Ag]NO3.1.5H2O, J. Chem. Soc., DaltonTrans., 1996, 2329-2333.[Crossref]
  • [25] Navarro J.A.R., Freisinger E., Lippert B., From simple trans-[a2Pt(2-hydroxypyrimidine)2]2+ (a = NH3, CH3NH2) complexes to structures of higher complexity. Molecular recognition of2-aminopyrimidine by hydrogen bond formation and reactivitytoward additional metal ions, Inorg. Chem., 2000, 39, 1059-1065.
  • [26] Rother I., Freisinger E., Erxleben A., Lippert B., trans-a2Pt(II)-(a = NH3, CH3NH2) modified purine base pairs and triples:Hydrogen bonding between self-complementary pairs andtriples and heterometal (Ag+)coordination leading to a 1 D helix,Inorg. Chim. Acta, 2000, 300-302, 339-352.
  • [27] Rother I.B., Willermann M., Lippert B., Canonical andunconventional pairing schemes between bis(nucleobase)complexes of trans-a2PtII:Artificial nucleobase quartets andC--H. . .N bonds, Supramol. Chem., 2002, 14, 189-197.
  • [28] Lippert B., Neugebauer D., A heteronuclear (Pt4,Ag) complexof 1-methyluracil and its conversion into a crystalline platinumblue, Inorg. Chem., 1982, 21, 451-452.
  • [29] Melník M., Structural isomerism of copper(II) complexes. Coord.Chem. Rev., 1982, 47, 239-261.
  • [30] Merino R.I., A polymeric platinum (II)-thallium (I) complexstabilized by alkynyl-thallium and platinum-thallium bondinginteractions, Inorg. Chem., 1997, 36, 6461-6464.
  • [31] Krogmann K., Hausen H.D., Strukturen mit Pt-Ketten, I.„Violettes” Kaliumtetracyanoplatinat, K2[Pt(CN)4]X0,3 • 2,5H2O (X = Cl, Br), Z. Anorg. Allg. Chem., 1968, 358, 67-81.
  • [32] Reis A.J.,Jr., Petersen SW., Crystal and molecular structure ofpotasium platine cyano complex. Annal. NY Acad. Sc., 1978, 313,560-563.
  • [33] D.W. Knoeppel, S.G. Shore, Inorg. Chem., 35, 1747 (1996).
  • [34] Du B., Meyers E.A., Shore S.G., , Syntheses and StructuralCharacterizations of Sheet- and Column-like Lanthanide−Transition Metal Arrays: The Effect of Hydrogen Bonding on theStructure When K+ Is Replaced by [NH4]+, Inorg. Chem., 2001,40, 4353-4360.
  • [35] Knoeppel D.W. Shore S.G. Unusual One-DimensionalLadder Structures Containing Divalent Europium and theTetracyanometalates Ni(CN)42- and Pt(CN)42-. Inorg. Chem.,1996, 35 (18), 5328–5334
  • [36] Munakata M., Zhang. J.Ch., Ino I., Kuroda-Sowa T., Mackawa M.,Suenaga Y., Oiji N., 1-D cyano-bridged heterometallic complexesconsisting of 1,4,8,11-tetraazacyclotetradecanesilver(II) andtetracyanopalladium(II) or tetracyanoplatinum(II), Inorg. Chim.Acta, 2001, 317, 268-275.
  • [37] Balch A.L., Fung E.Y., Nagle J.K., Olmstead M.M., RowleyS.P., Lead(II)/platinum(II) complexes with and without Pb-Ptinteractions, Inorg. Chem., 1993, 32, 3295-3299.
  • [38] Krogmann K., Stephan D., Strukturen mit Pt-Ketten. III. Erdalkalitetracyanoplatinate(II), Z. Anorg. Allg. Chem., 1968, 362, 290-300.
  • [39] Falvello L.R., Garde R., Tomás M., Synthesis and Crystal Structureof the 2-D Polymer {Cu(bipy)Pt(CN)4}∞ and Its Relationship tothe Tetranuclear Compound [{Cu(bipy)(H2 O)Pt(CN)4}2]•2H2O, J.Cluster Sc., 2000, 11, 125-133.
  • [40] Gable R.W., Hoskins B.F., Robson R., Synthesis and structureof [NMe4][CuPt(CN)4]: an infinite three-dimensional frameworkrelated to PtS which generates intersecting hexagonal channelsof large cross section, J. Chem. Soc., Chem. Commun., 1990,762-763.[Crossref]
  • [41] Niel V., Martinez – Agudo J.M., Muňoz M.C., Gaspar A.B., RealJ.A., Cooperative Spin Crossover Behavior in Cyanide-BridgedFe(II)−M(II) Bimetallic 3D Hofmann-like Networks (M = Ni, Pd,and Pt), Inorg. Chem., 2001, 40, 3838-3839
  • [42] Chen W., Fenghui L., You X.,[Pt(CN)2•2Me3SnCN•2Me3SnOH•bpe]n (bpe=trans-1,2-bis(4-pyridyl)ethylene), the First Double-Sinusoidal Platinum-TinCoordination Polymer, Chem. Letters, 2002, 31, 734-735.[Crossref]
  • [43] Morita M., Miyoshi T., Miyamoto T., Iwamoto T., Sasaki Y.,New Clathrate Compounds, Diamminemetal(Ni, Cu, Zn, or Cd)Tetracyanopalladate(II) and Tetracyanoplatinate(II) AromaticsClathrates. Bull. Chem. Soc. Jpn., 1967, 40, 1556-1556.[Crossref]
  • [44] Tokoro K., Ebihara M., Kawamura T., (CuX)n Helical Chains in[Pt(S2CNEt2)2Cu2X2] (X = Br, Cl), Acta Crystallogr., Sect. C,1995, 51, 2010-2013.
  • [45] Ebihara M., Sakurai K., Kawamura T., Katayama H., Masuda H.,Taga T., Covalent Bonding of Two Ag(I) Atoms to a Square-PlanarPt(II) Atom in [Pt3(S2CNEt2)6Ag2](ClO4)2, Chem. Letters, 1990,19, 415-418.[Crossref]
  • [46] Gleizes A., Verdaguer M., Structurally ordered bimetallic compounds: synthesis,crystal and molecular structures, and magnetic properties ofAMn(S2C2O2)2(H2O)3.4.5H2O (A = copper, nickel, palladium,or platinum), J. Amer. Chem., Soc., 1984, 106, 3727-3737.
  • [47] Li X., Dou J.M., Liu Y., Zhu L.Y., Zheng P.J., A novel PtII–dibenzo-18-crown-6 (DB18C6) complex, Acta Crystallogr., Sect. C, 2000,56, 1185-1187.
  • [48] Liu Y., Dou J.M., Zhuh L.Y., Sun D.Z., Zheng P.J. [K(18C6)]2[Pt(SCN)4](H2O): A novel one-dimensional coordination polymer with K-Nbonds. Ind.J. Chem.-A 2000, Vol.39A, 983-984.
  • [49] Spevak V.N., Lobadynk V.I., Skvortsov A.N., Konovalov V.E.,Beĺskii V.K., Skvortsov N.K. AN;H-1 and C-13 NMR and CDspectra of platinum complexes with (+)-methyl p-tolyl sulfoxide.Molecular structure and absolute configuration of potassium(-)-trichloro{S-methyl p-tolyl sulfoxide}platinate(II). Rusian J.General Chem., 1999, 69, 715-720
  • [50] Yamaguchi T., Yamazaki F., Ito T., A Helical Metal−Metal BondedChain via the Pt--Ag Dative Bond, J. Amer. Chem., Soc., 2001,123, 743-744.
  • [51] Freisinger E., Schneider A., Drumm M., Hegmans A., Meier S.,Lippert B., Exocyclic oxygen atoms of platinated nucleobasesas binding sites for alkali metal ions, J. Chem. Soc., DaltonTrans., 2000, 3281-3287.E. Freisinger, A. Schneider, M. Drumm,A. Hegmans, S. Meier, B. Lippert, J. Chem. Soc., Dalton Trans.,3281 (2000).[Crossref]
  • [52] Usón R., Forniés J., Tomás M., Casas J.M., Cotton F.A., FalvelloL.R., Synthesis and molecular structure of (NBu4)x[Pt(C6Cl5)2(μ-Cl)2Aglx: A novel chain polymeric compound, Polyhedron, 1986,5, 901-902.[Crossref]
  • [53] Yamazaki S., Deeming A.J., Hursthouse M.B., Malik K.M.A.,Linear co-polymerisation of trans-[Pt(C2But)2(PMe2Ph)2] withcopper(I) chloride, Inorg. Chim. Acta, 1995, 235, 147-150.
  • [54] Yamazaki S., Deeming J., Speel D.M., Hibbs D.E., HursthouseM.B., Malik K.M.A., Rings and linear polymers formed byaddition of silver perchlorate to trans-[Pt(C[triple bond, lengthas m-dash]CR)2(PMe2Ph)2 ] (R = But, H), Chem. Commun., 1997,177-178.[Crossref]
  • [55] Al-Resayes S.I., Hitchcock P.B., Nixon J.F., Synthesis, crystal,and molecular structure of the novel infinite chain mixedmetal carbene complex [Pd(μ-Cl)2Pt{C(PPh2)2}]n derived fromco-ordinated bis(diphenylphosphino)methane (dppm), J. Chem.Soc., Chem. Commun., 1986, 1710-1711.[Crossref]
  • [56] Strickler P., Die Kristallstruktur eines polynuclearen Silber-Platin-Mercaptophosphin-Komplexes, Helv. Chim. Acta, 1969,52, 270-279.[Crossref]
  • [57] Mason R., Robertson G.B., Pauling P.J., Molecular and crystalstructure of potassium bisacetylacetonatochloroplatinate(II), J.Chem. Soc. A, 1969, 485-492.[Crossref]
  • [58] Usón R., Forniés J., Tomás M., Ara I., Synthesis and Reactivity ofa New Class of Neutral Polymeric Complexes [PtAgX2(C6Cl5)L]x.Crystal Structure of [PtAgCl2(C6Cl5)PPh3]x.cntdot.1.5xCH2Cl2,Inorg. Chem., 1994, 33, 4023-4028.
  • [59] Appleton T.G., Byriel K.A., Hall J.R., Kennard C.H.L.,Lynch D.E., Sinkinson J.A., Smith G., Reactions of di- andtrimethylplatinum(IV) complexes with N-(phosphonomethyl)glycine (glyphosate) and iminobis(methylenephosphonic acid).Crystal structures of three dimethylplatinum(IV) complexes withN-(phosphonomethyl)glycine coordinated facially, Inorg. Chem.,1994, 33, 444-455.
  • [60] Piccinin A., Toussaint J.,Crystal structure of polymericK2Pt(CN)5.3H2O complex. Bull. Soc. Roy. Sc. Liège, 1967, 36,122-124.
  • [61] Levy Ch.J., Vittal J.J., Puddephatt R.J., Synthesis andCharacterization of Group 14−Platinum(IV) Complexes,Organometallics, 1996, 15, 2108-2117.[Crossref]
  • [62] Dahlenburg L., Mertel S., Chiral chelate phosphanes: XI.Application of cyclopentane-based C2 chiral bis(phosphane)ligands C5H8(PR2)2 to Pt-Sn-catalyzed styrene hydroformylation,J. Organomet. Chem., 2001, 630, 221-243.
  • [63] Farkas E., Kollár L., Moret M., Sironi A., Halogen Exchange inPlatinum−Phosphine−Tin(II) Halide Systems. Characterizationof the Novel PtI(SnCl3)[(2S,4S)-2,4-bis(diphenylphosphino)pentane] Complex, Organometallics, 1996, 15, 1345-1350.[Crossref]
  • [64] Stewart C.A., Arduengo A.J., III., A new class of pnicogentransitionmetal adducts: a stereo active lone pair at a 10-Sb-4antimony center, Inorg. Chem., 1986, 25, 3847-3848.
  • [65] Fackler J.C., Jr., Raptis R.G., Murray H.H., Heterobimetallicpyrazolato complexes: The syntheses and crystal structuresof cis-(PPh3)2ClPtII(3,5-Ph2pz), cis-(PPh3)2BrPtII(μ-3,5-Ph2pz)CuICl, cis-(PPh3)2ClPtII(μ-3,5-Ph2pz)AgICl and cis-(PPh3)2BrPtII(μ-3,5-Ph2-4-Br-pz)AuIBr (pz=pyrazolato anion),Inorg. Chim. Acta, 1992, 193, 173-183.
  • [66] Woo L.K., Maurya M.R., Jacobson R.A., Yang S., RingroseS.L., Mono- and dinuclear complexes of a new binucleatingporphyrin, .alpha.,.alpha.-5,15-bis(o-(nicotinoylamino)phenyl)-2,8,12,18-tetraethyl-3,7,13,17-tetramethylporphyrin. Crystalstructures of a mononuclear nickel(II) complex and a binuclearcopper-platinum complex, Inorg. Chem., 1992, 31, 913-919.
  • [67] Berardini M., Emge T.J., Brennan J.G., Heterobimetallic platinumtitaniumcomplexes: potential anticancer drugs, Inorg. Chem.,1993, 32, 2724-2728.
  • [68] Albinati A., Naegeli R., Togni A., Venanzi L.M., Mono- anddi-hydrido-bridged platinum(II)-tungsten(IV) complexes.Synthesis and X-ray crystal structure of [Cp2W(μ-H)2PtPh(PEt3)][BPh4] and [Cp2(H)W(μ-H)PtPh(PEt3)2][BPh4], J. Organomet.Chem., 1987, 330, 85-100.
  • [69] Pettinari C., Marchetti F., Cingolani A., Troyanov S.I.,Drozdov A., Heteropolymetallic compounds containing1,1′-bis(diphenylphosphino)ferrocene (DPPF ) and pyrazolateligands: synthesis, spectroscopic characterization andreactivity. Crystal and molecular structure of [(DPPF )Pt(az)2][azH = pyrazole (pzH) or 3,5-dimethylpyrazole] and [(DPPF )Pt(μ-pz)2CdI2], J. Chem. Soc., Dalton Trans., 1998, 3335-3342.[Crossref]
  • [70] Maienza F., Wörle M., Steffanut P., Mezzetti A., Spindler F.,Ferrocenyl Diphosphines Containing Stereogenic PhosphorusAtoms. Synthesis and Application in the Rhodium-CatalyzedAsymmetric Hydrogenation, Organometallics, 1999, 18, 1041-1049.[Crossref]
  • [71] Dong-Youn Noh, Eun-Me Seo, Ha-Jin Lee, Hong-Young Jang,Moon-Gun Choi, Young-Hwan Kim, Jongke Hong, Synthesesand characterization of heterobimetallic complexes (dppf)Pt(dithiolate) (dppf: bis(diphenylphosphino)ferrocene); X-raycrystal structures of (dppf)PtL where L=dmit, phdt and i-mnt,Polyhedron, 2001, 20, 1939-1945.
  • [72] Hodgson M.J., Healy P.C., Williams M.L., Arnold D.P., Peripherallymetallatedporphyrins: preparations, spectroscopic propertiesand structural studies of trans-[PtBr(MDPP)(PPh3)2] (DPP =dianion of 5,15-diphenylporphyrin, M = MnCl, Co, Ni, Zn) andrelated meso-η1-organoplatinum porphyrins, J. Chem. Soc.,Dalton Trans., 2002, 4497-4504.[Crossref]
  • [73] Hutton A.T., Shebanzadeh B., Shaw B.L., Symmetrical η1–, orσ–π-acetylide bridges in bimetallic μ-Ph2PCH2PPh2(dppm)complexes: crystal structures of [MePt(μ-η1–C[triple bond,length half m-dash]CMe)(μ-dppm)2PtMe][BF4] and [CIPT(μ-σ–π-C[triple bond, length half m-dash]CMe)(μ-dppm)2Rh(CO)][PF6],J. Chem. Soc., Chem. Commun., 1984, 549-551.[Crossref]
  • [74] Yamada Y., Uchida M., Miyashita Y., Fujisawa K., Konno T.,Okamoto K., Synthesis, Crystal Structures, and Some Propertiesof S-Bridged Pt(II)-M(III) (M = Co, Rh) Dinuclear Complexes withSquare-Planar and Octahedral Geometries, Bull Chem. Soc.Jpn., 2000, 73, 913-922.[Crossref]
  • [75] Baumann T.F., Nasir M.S., Sibert J.W., White A.J.A., OlmsteadM.M., Williams D.J., Barrett A.G.M., Hoffman B.M., solitaire-Porphyrazines: Synthetic, Structural, and SpectroscopicInvestigation of Complexes of the Novel BinucleatingNorphthalocyanine-2,3-dithiolato Ligand, J. Amer. Chem. Soc.,1996, 118, 10479-10486.[Crossref]
  • [76] Toronto D.V., Balch A.L., Formation of Trinuclear Complexes byAddition of Mercury(II) Halides and Gold(I) Halides to Pt2(.mu.-dpm)2(CN)2, Inorg. Chem., 1994, 33, 6132-6139.
  • [77] Zhaohni Li, Zhi-Heng Loh, Fong S.W.A., Yaw-Kai Yan, HendersonW., Mok K.F., Hor T.S.A., Ligand-stabilization of an unusualsquare-based pyramidal geometry of Cd(II) and Zn(II) in anheterometallic {MPt2S2} core (M = Cd, Zn), J. Chem. Soc., DaltonTrans., 2000, 1027-1031.
  • [78] Micklitz W., Müller G., Huber B., Riede J., Rashvau F., HeinzeJ., Lippert B., Trinuclear, mixed Pt2Pd-1-methyluracil and-1-methylthymine blues with +2.33 average metal oxidationstate. Preparation, crystal structures, and solution studies, J.Amer. Chem. Soc., 1988, 110, 7084-7092.[Crossref]
  • [79] Chen W., Matsumoto K., Synthesis and Structural Characterizationof Trinuclear, Amidate-Bridged Heterobimetallic Complexes[{Pt(NH3)2(NHCOtBu)2}2M]Xn (M = Mn, Fe, Co, Ni, Cu; X = BF4−,ClO4−; n = 2 or 3), Eur. J. Inorg. Chem., 2002, 2664-2670.
  • [80] Usón R., Forniés J., Falvello L.R., Tomás M., Casas J.M.,Martin A., Synthesis and structure of tetrabutylammoniumhexakis(perfluorophenyl)bis(.mu.-tetrahydrothiophene)diplatinum argentate(1-), a trinuclear compound displaying twostructurally different anions in the solid state, Inorg. Chem.,1993, 32, 5212-5215.
  • [81] Yoshida T., Tanaka S., Adachi T., Yoshida T., Onitsuka K.,Sonogashira K., Reactions of 1,1′-Ferrocenediylbis{chloro-[(1,2,5,6-η)-1,5-cyclooctadiene]}diplatinum withTriarylphosphane and Molecular Oxygen, Angew. Chem. Int. Ed.Engl., 1995, 34, 319-321[Crossref]
  • [82] Weiss D., Steinke T., Winter M., Fischer R.A., Fröhlich N., UddinJ., Frenkzing G., [(dcpe)Pt(ECp*)2] (E = Al, Ga): Synthesis,Structure, and Bonding Situation of the First Aluminum(I) andGallium(I) Complexes of Phosphine-Substituted Transition MetalCenters, Organometallics, 2000, 19, 4583-4588.[Crossref]
  • [83] Bachert I., Bartusseck I, Braunstein P., Guillon E., Rosé J.,Kickelbick G. Synthesis of Co2Pt, Co2Pd and MoPd2 mixed-metalclusters with the P–N–P assembling ligands (Ph2P)2NH (dppa)and (Ph2P)2NMe (dppaMe). Crystal structure of [Co2Pt(μ3-CO)(CO)6(μ-dppa)]. J. Organomet. Chem., 1999, 580, 257–264.
  • [84] Kuwata S., Mizobe Y., Hidai M., Reactions of a dirutheniumcomplex bridged by disulfide and thiolate ligands with zerovalentnoble metal complexes. Syntheses of mixed metalsulfide-thiolate clusters containing trinuclear PtRu2 andtetranuclear Pd2Ru2 cores, J. Amer. Chem. Soc., 1993, 115,8499-8500.[Crossref]
  • [85] Deeming A.J., Cockerton B.R., Doherty S., Substitutionof chloride in [PtCl2(PET3)2] by the chiral anionic ligand[Mo(CO)5(PPhH)]− to give mixed platinum-molybdenumcompounds and a 31P1H∗ NMR analysis of their fluxionality.X-ray crystal structure of [PtCl(PEt3)2(μ-PPhH)Mo(CO)5] andtrans-[Pt(PEt3)2(μ-PPH)2Mo(CO)52], Polyhedron, 1997, 16, 1945-1956.
  • [86] Bruce M.I., Hall B.C., Low P.J., Smith M.E., Skelton B.W., WhiteA.H., Heterometallic complexes containing C4 chains. X-raystructures of {Cp(OC)3W}C≡CC≡C{Ir(CO)(PPh3)2(O2)} and cis-Pt{C≡CC≡C[W(CO)3Cp]}2(PEt3)2, Inorg. Chim. Acta, 2000, 300-302, 633-644.
  • [87] Larsen A.O., Taylor B.A., White P.S., Cagné M.R., AsymmetricSynthesis of Rigid C2-Symmetric Bis(ferrocenyl) Diol andDiamine Ligands, Organometallics, 1999, 18, 5157-5162.[Crossref]
  • [88] McAdam C.J., Blackie E.J., Morgan J.L., Mole S.A., Robinson B.H.,Simpson J., Acetylides of cycloplatinated ferrocenylamines;synthesis and redox chemistry, J. Chem. Soc., Dalton Trans.,2001, 2362-2369.[Crossref]
  • [89] Stepnička P., Podlaha J., Geypes R., Polášek M., Synthesis andstructural characterization of Pd(II) and Pt(II) complexes withP-bonded 1‘-(diphenylphosphino)- ferrocenecarboxylic acid, J.Organomet. Chem., 1998, 522, 293-301.
  • [90] Antonova A.B., Johansson A.A., Deykhina N.A., PogrebnyakovD.A., Pavlenko N.I., Rubaylo A.I., Dolgushin F.M., PetrovskiiP.V., Ginzburg A.G., Chemistry of vinylidene complexes. XIII.The reaction between Cp(CO)2MnPt(μ-CCHPh)(η2-dppm) andFe2(CO)9: simultaneous formation of the μ3-vinylidene MnFePtand μ4-vinylidene PtFe3 clusters. Crystal structure of (η5-C5H5)MnFePt(μ3-C=CHPh)(CO)6[η1-Ph2PCH2P(O)Ph2], J. Organomet.Chem., 1999, 577, 238-242.
  • [91] Schuh W., Kopacka H., Wurst K., Peringer P., Chemistry atthe Sterically Shielded Mercury Centre of the [(η4-pp3)PtHg]Fragment, Eur. J. Inorg. Chem., 2001, 2399-2404.
  • [92] Wa-Hung Leung, Chim J.L.C., Wink-Tak Wong, Syntheses andcrystal structures of bi- and tri-metallic complexes containinga trioxoosmium(VIII) moiety, J. Chem. Soc., Dalton Trans., 1997,3277-3282.
  • [93] Usón R., Forniés J., Tomás M., Usón I., (NBu4)[Sn{Pt(μ-Cl)(C6F5)2}3], an Unusual Cluster with Three PtII [RIGHTWARDSARROW] SnII Bonds, Angew. Chem. Int. Ed. Engl., 1990, 29,1449-1450.[Crossref]
  • [94] Bender R., Braunstein P., Jud J.M., Dusausoy Y., Organometalliccomplexes with metal-metal bonds. 19. Comparison of twostrategies towards the syntheses of platinum mixed-metalclusters. Reactivity of linear M-Pt-M and Mn-Pt-Mn complexes.X-ray crystal structures of Pt2M2(.eta.5-C5H5)2(.mu.3-CO)2(.mu.-CO)4(PEt3)2 with M = Cr, Mo, and W, Inorg. Chem., 1984,23, 4489-4502.
  • [95] Blum T., Braunstein P., Tiripicchio A., Tiripicchio-Camellini M.,Reactivity of molybdenum-platinum bonds toward PPh2H:Synthesis of phosphido-bridged, heterometallic complexes.Molecular structures of [(.eta.-C5H5)2Mo2Pt(.mu.-PPh2)2(CO)5].cntdot.1/2C7H8 and of the hydrido, tetranuclear, bent-chaincomplex [(.eta.-C5H5)MoPt(H) (.mu.-PPh2)2(CO)2]2 (Ph = C6H5),Organometallics, 1989, 8, 2504-2513.[Crossref]
  • [96] Farrugia L.J., Green M., Harkey D.R., Murray M., OrpenA.G., Stone F.G.A., Chemistry of the unsaturated clustercompound [Os3Pt(μ-H)2(CO)10{P(cyclo-C6H11)3}]; X-ray crystalstructures of [Os3Pt(μ-H)2(CO)11{P(cyclo-C6H11)3}], [Os3Pt(μ-H)4(CO)10{P(cyclo-C6H11)3}], and [Os3Pt(μ-H)2(μ-CH2)(CO)10–{P(cyclo-C6H11)3}](two isomers), J. Chem. Soc., Dalton Trans.,1985, 177-190.[Crossref]
  • [97] Farrugia L.J., Green M., Hankey D.R., Orpen A.G., Stone F.G.A.,Reversible addition of hydrogen and carbon monoxide to a closotriosmiumplatinumcluster: X-ray crystal structures of [Os3Pt(μ-H)4(CO)10{P(C6H11)3}] and [Os3Pt(μ-H)2(CO)11{P(C6H11)3}], J.Chem. Soc., Chem. Commun., 1983, 310-312.[Crossref]
  • [98] Adams R.D., Hor T.S.A., Cluster synthesis. 7. Role of bridgingsulfido ligands in the synthesis of platinum osmium carbonylcluster compounds, Inorg. Chem., 1984, 23, 4723-4732.
  • [99] Farrugia L.J., MacDonald N., Peacock R.D., Structure of1,2;1,3-di-μ-carbonyl-1,1,2,2,3,3,4-heptacarbonyl-2,3-μ-η3-cyclooctenyl-2,4-μ-hydrido-4-tricyclohexylphosphinetetrahedro-trirutheniumplatinum, Acta Crystallogr., Sct. C,1991, 47, 2561-2564.
  • [100] Antognazza P., Beringhelli T., DÁlfonso G., Minoja A., Ciani G.,Moret M., Sironé A., Rhenium-platinum mixed-metal clusters.Synthesis and solid-state structural characterization of [Re2Pt(.mu.-H)2(CO)8(COD)] and [Re3Pt(.mu.-H)3(CO)14] (COD =1,5-cyclooctadiene), Organometallics, 1992, 11, 1777-1784.[Crossref]
  • [101] Ciani G., Moret M., Sironi A., Beringhelli T., D’lfonso G.,Della Pergola R., Stepwise addition of PtPPh3 fragmentson [Re2(CO)10]. X-Ray crystal structures of the complexes[Re2Ptn(μ-CO)2n(CO)10 – 2n(PPh3)n](n= 2, 3), the firstexamples of tetra-and penta-nuclear rhenium–platinum mixedmetalclusters, J. Chem. Soc., Chem. Commun., 1990, 1668-1670.[Crossref]
  • [102] Adams R.D., Chen G., Lii J.Ch., Wu W., Cluster synthesis. 30. Newplatinum-osmium carbonyl cluster complexes from the reactionof Os3(CO)10(NCMe)2 with bis(cyclooctadiene)platinum, Inorg.Chem., 1991, 30, 1007-1013.
  • [103] Douglas G., Jennings M.C., Manojlovic-Muir L., PuddephattR.J., Synthesis and structure of the cluster[bis(diphenylphosphino)methane][(triphenylphosphine)gold], containing both platinum-gold and platinumsilverbonds, Inorg. Chem., 1988, 27, 4516-4520.
  • [104] Freeman M.J., Miles A.D., Murray M., Orpen A.G., Stone F.G.A.,The synthesis and x-ray crystal structure of the hexanuclearmetal cluster complex [Ir3Pt3(μ-CO)3(CO)3(η-C5Me5)3],Polyhedron, 1984, 3, 1093-1097.[Crossref]
  • [105] Rauter H., Mutikainen I., Blomberg M., Lock C.J.L., Amo-OchoaP., Freisinger E., Zangrndo L.E., Chiarprin E., Lippert B., CyclicMetal Complexes of Nucleobases and Other Heterocycles:Molecular Boxes, Rectangles, and Hexagons, Angew. Chem. Int.Ed. Engl., 1997, 36, 1296-1301.
  • [106] Espinet P., Forniés J., Martinez F., Tomás M., Lalinde E., MorenoM.T., Ruitz A., Welch A.J., Polynuclear platinum–silver, –copper, and –gold acetylide complexes. Molecular structureof [Pt2Ag4(C[triple bond, length half m-dash]CBut)8], J. Chem.Soc., Dalton Trans., 1990, 791-798.[Crossref]
  • [107] Adams R.D., Wu W., Cluster synthesis 37-Platinum-rutheniumcarbido-cluster complexes: The syntheses and structuralcharacterizations of PtRu5(C)(CO)16, Pt2Ru5(C)(CO)13(COD)2,and Pt3Ru5(C)(CO)14(COD)2, J. Cluster Sc., 1991, 2, 271-290.
  • [108] Hermans S., Khimyak T., Johnson B.F.G., High yield synthesis ofRu–Pt mixed-metal cluster compounds, J. Chem. Soc., DaltonTrans., 2001, 3295-3302.[Crossref]
  • [109] Adams R.D., Captain B., Fu W., Pellechia P.J., Facile dynamicalintramolecular exchange of a phosphine ligand between twodifferent metal atoms, Chem. Commun., 2000, 937-938.[Crossref]
  • [110] Adams R.D., Wu W., An unusual electron-rich carbido platinumrutheniumcluster from the reaction of diphenylacetylenewith PtRu5(CO)16(.mu.6-C). Synthesis and crystallographiccharacterizations of PtRu5(CO)13(.mu.-PhC2Ph)(.mu.3-PhC2Ph)(.mu.5-C) and Ru6(CO)13(.mu.3-PhC2Ph)2(.mu.6-C),Organometallics, 1993, 12, 1238-1242.[Crossref]
  • [111] Adams R.D., Wu W., Cluster synthesis. 34. Unsaturationin a high-nuclearity platinum-osmium carbonyl clustercomplex. Studies of the synthesis, structure, and reactivity ofPt2Os4(CO)11(COD)2, Inorg. Chem., 1991, 30, 3605-3612.
  • [112] Navaro J.A.R., Freisinger E., Lippert B., [(Ethylenediamine)Pt(uracilate)]4 – A Metal Analogue of Calix[4]arene:Coordination Chemistry of Its 1,3-Alternate Conformer towardsFirst-Row Transition-Metal Ions, Eur. J. Inorg. Chem., 2000, 147-151.
  • [113] Adams R.D., Li Z., Lii J.Ch., Wu W., Cluster synthesis. 40. Newhigh-nuclearity platinum-ruthenium carbonyl clustercomplexes. Synthesis and structural characterizations ofRu8Pt2(CO)23(.mu.3-H)2, Ru7Pt3(CO)22(.mu.3-H)2, andRu8Pt2(CO)21(.mu.3-.eta.2-CO)2(dppe)(.mu.-H)2 with a newtype of triply bridging CO ligand and a new layered clustercomplex Ru6Pt3(CO)21(.mu.-CO)(.mu.3-H)2, Organometallics,1992, 11, 4001-4009.
  • [114] Adams R.D., Barnard T., Li Z., Wu W., Yamamoto J.H., Thesynthesis and structural analysis of the new high nuclearityplatinum-ruthenium cluster complex Pt2Ru8(CO)18(μ3−EtC2Et)2(μ4−EtC2Et) containing three alkyne ligands, J. ClusterSc., 1994, 5, 551-564.
  • [115] Rubinstein L.I., Pignolet L.H., Kinetic Investigation ofHomogeneous H2−D2 Equilibration Catalyzed by Pt−Au ClusterCompounds. Characterization of the Cluster [(H)Pt(AuPPh3)9](NO3)2, Inorg. Chem., 1996, 35, 6755-6762.
  • [116] Ceriotti A., Demartin F., Longoni G., Manassero M., MarchionnaM., Piva G., Sansoni M., Synthesis and Structure of the[Ni38Pt6(CO)48H6−n]n− (n=5, 4) Ions: Ni-Pt Clusters as Modelsfor “Cherry” Crystallites, Angew. Chem. Int. Ed. Engl., 1985, 24,697-698.[Crossref]
  • [117] Adams R.D., Pompeo M.P., Wu W., Cluster synthesis. 33.New platinum-osmium carbonyl cluster complexes fromPt2Os5(CO)17(.mu.-H)6: synthesis and characterization ofPtOs5(CO)15(.mu.3-S)(.mu.-H)6, PtOs5(CO)18(.mu.-H)4, andPtOs4(CO)15(.mu.-H)2, Inorg. Chem., 1991, 30, 2899–2905.
  • [118] Pasynskii A.A., Kolobkov B.I., Nefedov S.E., Eremenko I.L.,Koltun E.S., Ivanov A.I., Yu. T. Struchkov, Synthesis andmolecular structures of S2Fe2(CO)6 heterometallic derivatives,containing (Ph3P)2Pt or CpRe(CO) fragments, J. Organomet.Chem., 1993, 454, 229-236.
  • [119] Lindner E., Kehrer U., Steimann N., Ströbele M., Preparation,properties, and reactions of metal-containing heterocycles:Part CV. Synthesis and structure of polyoxadiphosphaplatinaferrocenophanes, J. Organomet. Chem., 2001, 630, 266-274.
  • [120] Liu H., Tan A.L., Mok K.F., Mak T.C.W., Batsanov A.S., HowardJ.A.K., Hor T.S.A., From Aggregates to Clusters. FacileFormation of Hetero-Metal−Metal Bonds through ReductiveDesulfurization by CO in a Decapacitative Transformation of a{Pt2MS2} Tbp Frame to a {Pt2MS} Tetrahedral Core (M = Ag, Cu,and Ru), J. Amer. Chem. Soc., 1997, 119, 11006-11011.[Crossref]
  • [121] Ranatunge-Bandarage P.R., Duffy N.W., Johnston S.M.,Robinson B.H., Simpson J., Synthesis and stereochemistry ofbis(platinum) complexes of ferrocenylamines, Organometallics,1994, 13, 511-521.[Crossref]
  • [122] Vicente J., Chicote M.T., Huertas S., Jones P.G., Fischer A.K,Heterodi- [MAg, MAu (M = Pd, Pt)], Tri- [PdAg2, PtAg2, PtAu2,Pt2M (M = Ni, Pt, Cd, Hg)], and Tetranuclear (Pt2Ag2, Pt2Au2)1,1-Ethylenedithiolato Complexes, Inorg. Chem., 2001, 40,6193-6200.
  • [123] Vicente J., Chicote M.T., Huertas S., Bautista D., Jones P.G.,Fischer A.K., Mononuclear (Pd, Pt), Heterodinuclear (PdAg,PtAg), and Tetranuclear (Pd2Ag2, Pt2Ag2) 1,1-EthylenedithiolatoComplexes, Inorg. Chem., 2001, 40, 2051-2057.
  • [124] Green M., Hankey D.R., Murray M., Orpen A.G., Stone F.G.A.,Synthesis, dynamic behaviour, and molecular structuresof μ-methylene platinumtriosmium complexes; X-raycrystal structures of two isomers of [Os3Pt(μ-H)2(μ-CH2)(CO)10{P(C6H11)3}], J. Chem. Commun., 1981, 689-691.[Crossref]
  • [125] Adams R.D., Chen G., Wu W., The synthesis and structuralanalysis of Pt2Ru4(CO)18 and the products obtained from itsreactions with 1, 2-bis(diphenylphosphino)ethane, J. ClusterSc., 1993, 4, 119-132.
  • [126] Antonucci V., Aricó A.S., Calderazzo F., Labella L., Marchetti F.,A New Polymorph of the Heteronuclear Cluster Ru4Pt2(CO)18, J.Cluster Sc., 2001, 12, 293-301.
  • [127] Kappen T.G.M.M., Schlebos P.P.J., Bour J.J., Bosman W.P.,Beurskens G., Smits J.M.M., Beurskens P.T., Steggerda J.J.,Cluster Growth: Some Representative Reactions. CrystalStructures of [Pt(H)(AgNO3)(AuPPh3)8](NO3) and [Pt(H)(AgNO3)2(AuPPh3)8](NO3), Inorg. Chem., 1995, 34, 2121-2132.
  • [128] Melník M., Holloway C.E., Stereochemistry of platinumcoordination compounds, Coord. Chem. Rev., 2006, 250, 2261-2270.
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