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Crystallographic and structural characterization of heterometallic platinum clusters. Part IX. Heterooligonuclear Pt clusters

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This review classifies and analyzes over thirty
heterooligonuclear platinum clusters with a wide variety
of metal frameworks, from twelve to forty-four. There are
thirteen heterometals (Ge, Sn, Hg, W, Mo, Ru, Rh, Pd,
Os, Ni, Cu, Ag, Au) which are the partners of platinum.
The clusters mostly crystallize in monoclinic (36,4%)
and triclinic (30,3%) crystal classes. Their structures
are complex, with platinum most commonly preferring
interstitial sites, such as the centroids of icosahedrons.
There are examples of distortion isomerism. The most
common ligands are CO and PPh3, and it is interesting that
the mean Pt-CO and M-CO bond distances are identical
at 1.84 Å. In contrast, the mean Pt-μCO and M-μCO
are of values of 2.02 and 1.97 Å, respectively, while the
Pt-PPh3 and M-PPh3 bond distances are 2.30 and 2.28 Å,
respectively. The shortest Pt-Pt, Pt-M (non-transition) and
Pt-M (transition) bond distances are 2.559(2) Å, 2.412(2) Å
(M = Ge) and 2.510(2) Å (M = Ni).
Physical description
11 - 8 - 2014
15 - 5 - 2014
20 - 1 - 2015
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