Synthesis of bio-active titanium oxide coatings stimulated by electron-beam plasma

• Authors: Tatiana Vasilieva , Igor Sokolov , Andrey Sigarev , Aung Tun Win
• Languages of publication: EN

Abstracts

EN

Advantages of the electron-beam plasma (EBP) for production of bioactive titanium oxide coatings were experimentally studied. The coatings were synthesized in EBP of oxygen on the surface of plane titanium substrates. A number of analytical techniques were used to characterize morphology, chemical composition, and structure of the synthesized titanium oxide. The analysis showed the titanium oxide (IV) in the rutile form to predominate in the coatings composition. The samples with plasmachemically synthesized TiO2-coatings were more hydrophilic than untreated titanium. The effect was stable during two weeks and then the degradation of the wettability began. The EBP-stimulated TiO2 synthesis improved the hydroxyapatite formation on the surface of plane titanium substrates. The EBP-stimulated TiO2 synthesis is promising technique to produce bioactive coatings on the surface of titanium medical dental and bone implants. The computer simulation of plasma-surface interaction was carried out to predict the plasma composition, to find the spatial distribution of the sample temperature, and to calculate the flows of the chemically active plasma particles bombarding the tube wall. The flows of atomic and singlet oxygen were found to be the most intensive and, therefore, these particles are likely to be responsible for the formation of the biocompatible TiO2-coaings.

Keywords

EN

Titanium oxide (IV); rutile; hydroxyapatite; oxygen species; computer simulation

• Publisher: De Gruyter Open
• Journal: Open Chemistry
• Year: 2015
• Volume: 13
• Issue: 1

Dates

online

17 - 11 - 2014

accepted

17 - 3 - 2014

received

29 - 12 - 2013

Contributors

author

Tatiana Vasilieva

• Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia

author

Igor Sokolov

• Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia

author

Andrey Sigarev

• Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia

author

Aung Tun Win

• Moscow Institute of Physics and Technology, 141700 Dolgoprudny, Moscow region, Russia

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Identifiers

DOI

10.1515/chem-2015-0015