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2015 | 2 | 1 |
Article title

Chiral Counterion Strategy in Cu-Catalyzed
Asymmetric Allylic Oxidation of Linear Alkenes

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Application of a chiral counter-ion strategy in
the Kharasch-Sosnovsky reaction is reported. Copper(I)
phosphates obtained from axially chiral, BINOL-derived
phosphoric acids were investigated as catalysts in the
enantioselective allylic oxidation of acyclic alkenes.
Good yields and high regioselectivity towards branched
allylic ester have been achieved. The chiral phosphates
investigated exhibited modest enantioselectivities.
Physical description
14 - 7 - 2015
25 - 9 - 2015
29 - 7 - 2015
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