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2015 | 2 | 1 |
Article title

Chiral Counterion Strategy in Cu-Catalyzed
Asymmetric Allylic Oxidation of Linear Alkenes

Content
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EN
Abstracts
EN
Application of a chiral counter-ion strategy in
the Kharasch-Sosnovsky reaction is reported. Copper(I)
phosphates obtained from axially chiral, BINOL-derived
phosphoric acids were investigated as catalysts in the
enantioselective allylic oxidation of acyclic alkenes.
Good yields and high regioselectivity towards branched
allylic ester have been achieved. The chiral phosphates
investigated exhibited modest enantioselectivities.
EN
Publisher
Year
Volume
2
Issue
1
Physical description
Dates
received
14 - 7 - 2015
online
25 - 9 - 2015
accepted
29 - 7 - 2015
References
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Document Type
Publication order reference
YADDA identifier
bwmeta1.element.-psjd-doi-10_1515_asorg-2015-0005
Identifiers
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